Caires, Antonio Carlos FáveroMauro, Antonio Eduardo [UNESP]Moro, Antonio Carlos [UNESP]Legendre, Alexandre de Oliveira [UNESP]Ananias, Sandra Regina [UNESP]2014-05-202014-05-202006-07-01Química Nova. Sociedade Brasileira de Química, v. 29, n. 4, p. 750-754, 2006.0100-4042http://hdl.handle.net/11449/26000This work deals with the use of the cyclometallated compound [Pd(dmba)(N3)(PPh3)] in homogeneous catalytic processes comprising the reductive N-carbonylation of nitrobenzene and p-nitrotoluene to ethyl-phenylcarbamate and ethyl-4-methylphenylcarbamate, respectively. The cyclopalladated compound was also employed in the synthesis of urea derivatives by reacting p-nitrotoluene and m-nitrotoluene, respectively, with p-toluidine and and m-chloroaniline.750-754porcyclopalladated compoundhomogeneous catalytic processreductive N-carbonylationSíntese e emprego do ciclometalado [Pd(dmba)(N3)(PPh3)] em processos catalíticos envolvendo a n-carbonilação redutiva de nitroarenos a carbamatos e na síntese de derivados da uréiaSynthesis of [Pd(dmba)(N3)(PPh3)] and its use in catalytic processes involving the reductive n-carbonylation of nitroarenes to carbamates and in the synthesis of urea derivativesArtigo10.1590/S0100-40422006000400022S0100-40422006000400022Acesso abertoS0100-40422006000400022.pdf3300223970814448