In situ application of a cellulose bag and an ion exchanger for differentiation of labile and inert metal species in aquatic systems

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Data

2008-02-01

Autores

Goveia, Danielle [UNESP]
Rosa, Andre Henrique [UNESP]
Bellin, Iramaia Correa
Lobo, Fabiana Aparecida [UNESP]
Fraceto, Leonardo Fernandes [UNESP]
Frutuoso Roveda, Jose Arnaldo [UNESP]
Cruz Romao, Luciane Pimenta
Dias Filho, Newton Luiz [UNESP]

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Editor

Springer Heidelberg

Resumo

This work involved the development and application of a new analytical procedure for in-situ characterization of the lability of metal species in aquatic systems by using a system equipped with a diffusion membrane and cellulose organomodified with p-aminobenzoic acid groups (DM-Cell-PAB). To this end, the DM-Cell-PAB system was prepared by adding cellulose organomodified with p-aminobenzoic acid groups (Cell-PAB) to pre-purified cellulose bags. After the DM-Cell-PAB system was sealed, it was examined in the laboratory. The in-situ application involved immersing the DM-Cell-PAB system in two different rivers, enabling us to study the relative lability of metal species (Cu, Cd, Fe, Mn, and Ni) as a function of time and quantity of exchanger. The procedure is simple and opens up a new perspective for understanding environmental phenomena relating to the complexation, transport, stability, and lability of metal species in aquatic systems rich in organic matter.

Descrição

Palavras-chave

lability, metals, aquatic organic matter, water, speciation

Como citar

Analytical and Bioanalytical Chemistry. Heidelberg: Springer Heidelberg, v. 390, n. 4, p. 1173-1180, 2008.