Structure of copper(II) complexes adsorbed on functionalized polyhedral oligomeric silsesquioxane
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Data
2008-06-02
Autores
Dias Filho, Newton Luiz [UNESP]
Costa, Reginaldo Mendonca [UNESP]
Schultz, Mario Sergio
Título da Revista
ISSN da Revista
Título de Volume
Editor
Elsevier B.V. Sa
Resumo
The 3-amino-1,2,4-triazole-modified silsesquioxane nanoplatforms have been prepared and characterized. The silsesquioxane nanocages readily react with CuX(2) in aqueous solution to form copper complex-substituted silsesquioxanes. Adsorption isotherms of CuX(2) from aqueous solution were studied at 25 degrees C. The electronic and ESR spectral parameters indicated that the copper ion is in a distorted-tetragonal symmetry field. (C) 2007 Elsevier B.V. All rights reserved.
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Palavras-chave
copper complex, silsesquioxane, fuctionalized silsesquioxane, adsorption isotherms
Como citar
Inorganica Chimica Acta. Lausanne: Elsevier B.V. Sa, v. 361, n. 8, p. 2314-2320, 2008.