Temperature dependency of aqueous biphasic systems: An alternative approach for exploring the differences between Coulombic-dominated salts and ionic liquids
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2017-01-01
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E Silva, Francisca A.
Pereira, Jorge F. B. [UNESP]
Kurnia, Kiki A.
Ventura, Sónia P. M.
Silva, Artur M. S.
Rogers, Robin D.
Coutinho, João A. P.
Freire, Mara G.
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Herein we propose an alternative way to distinguish ionic liquids from Coulombic-dominated salts, based not on their upper limit melting temperature (100 °C), but on the trend of their phase-forming abilities to create aqueous biphasic systems as a function of temperature, in which a wider plethora of interactions can be appraised.
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Chemical Communications, v. 53, n. 53, p. 7298-7301, 2017.