Deposição de hidreto de silício sobre a zircônia em diferentes tempos: análise química, microestrutural e durabilidade da união ao cimento resinoso
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Data
2018-12-10
Autores
Monteiro, Jaiane Bandoli [UNESP]
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Editor
Universidade Estadual Paulista (Unesp)
Resumo
O objetivo deste estudo foi avaliar a Deposição Química na Fase Vapor Assistido por Plasma (PECVD) com hidreto de silício (SiH4) em zircônia VITA YZ HT em diferentes tempos, bem como os seus efeitos nas características superficiais do material e na união ao cimento resinoso antes e após a termociclagem. Blocos de zircônia Vita YZ HT foram obtidos, polidos, sinterizados e divididos em 5 grupos, de acordo com o tempo de PECVD (n = 31): Zr-30 (30s), Zr-60 (60s), Zr-120 (120s) e Zr-300 (300s). O grupo controle (Zr-0) não recebeu deposição. Análises de DRX, FTIR, EDS, FE-SEM, XPS, goniometria e perfilometria foram utilizadas para caracterização química e topográfica. O silano Monobond N foi aplicado na superfície e um cilindro de cimento resinoso (Variolink N) foi confeccionado (3 × 3 mm). Metade dos espécimes de cada grupo foi armazenada por 24 h ou submetida à termociclagem (6 × 10³ ciclos). Teste de resistência ao cisalhamento (SBS) foi realizado. Os resultados foram submetidos aos testes one-way Anova e Tukey (α = 0,05). Para os grupos experimentais, o XPS mostrou que a formação de ligações Si-O contribuiu para o aumento da Energia Livre de Superfície (ELS). MEV-FEG e EDS mostraram que quanto maior o tempo de deposição, maior a quantidade de silício na superfície, apresentando apenas fase tetragonal. Zr-60 e Zr-300 apresentaram maior e menor rugosidade superficial, respectivamente. O silício penetrou na microestrutura, causando maior concentração de tensão. A resistência de união ao cimento resinoso foi melhorada após todos os tempos de deposição da PECVD. Portanto, a técnica de PECVD com o composto químico SiH4 associada ao tratamento químico com primer universal baseado em metacrilato de silano é uma alternativa promissora para a manutenção da ligação entre cimento resinoso e zircônia HT.
The aim of this study was to evaluate the effect of Plasma-enhanced Chemical Vapor Deposition (PECVD) with silicon hydride (SiH4) on VITA YZ HT zirconia at different times, as well as its effects on material surface characteristics and bonding to resin cement before and after thermocycling. Blocks of VITA YZ HT zirconia were obtained, polished, sintered, and divided into five groups, according to PECVD time (n = 31): Zr-30 (30 s), Zr-60 (60 s), Zr-120 (120 s), and Zr-300 (300 s). The control group (Zr-0) did not receive deposition. XRD, FTIR, EDS, FE-SEM, XPS, goniometry, and profilometry analyses were used for chemical and topographic characterization. Monobond N silane was applied to the surface, and a cylinder of resin cement (Variolink N) was made (3 × 3 mm). Half of the specimens of each group were stored for 24 h or subjected to thermocycling (6 × 10³ cycles). A shear bond strength (SBS) test was performed. Results were subjected to one-way ANOVA and Tukey's tests (α = 0.05). For experimental groups, XPS showed that formation of Si-O bonds contributed to increased Surface Free Energy (SFE). FE-SEM and EDS showed that the longer the deposition time, the greater the amount of silicon on the surface, presenting only a tetragonal phase. Zr-60 and Zr-300 presented higher and lower surface roughnesses, respectively. The silicon penetrated the microstructure, causing higher stress concentrations. The bond strength to resin cement was improved after all PECVD deposition times. Thus, the PECVD technique with the chemical compound SiH4, associated with chemical treatment with universal primer based on silane methacrylate, is a promising alternative for maintaining bonding between resin cement and HT zirconia.
The aim of this study was to evaluate the effect of Plasma-enhanced Chemical Vapor Deposition (PECVD) with silicon hydride (SiH4) on VITA YZ HT zirconia at different times, as well as its effects on material surface characteristics and bonding to resin cement before and after thermocycling. Blocks of VITA YZ HT zirconia were obtained, polished, sintered, and divided into five groups, according to PECVD time (n = 31): Zr-30 (30 s), Zr-60 (60 s), Zr-120 (120 s), and Zr-300 (300 s). The control group (Zr-0) did not receive deposition. XRD, FTIR, EDS, FE-SEM, XPS, goniometry, and profilometry analyses were used for chemical and topographic characterization. Monobond N silane was applied to the surface, and a cylinder of resin cement (Variolink N) was made (3 × 3 mm). Half of the specimens of each group were stored for 24 h or subjected to thermocycling (6 × 10³ cycles). A shear bond strength (SBS) test was performed. Results were subjected to one-way ANOVA and Tukey's tests (α = 0.05). For experimental groups, XPS showed that formation of Si-O bonds contributed to increased Surface Free Energy (SFE). FE-SEM and EDS showed that the longer the deposition time, the greater the amount of silicon on the surface, presenting only a tetragonal phase. Zr-60 and Zr-300 presented higher and lower surface roughnesses, respectively. The silicon penetrated the microstructure, causing higher stress concentrations. The bond strength to resin cement was improved after all PECVD deposition times. Thus, the PECVD technique with the chemical compound SiH4, associated with chemical treatment with universal primer based on silane methacrylate, is a promising alternative for maintaining bonding between resin cement and HT zirconia.
Descrição
Palavras-chave
Materiais dentários, Zircônia, Silício, Envelhecimento, Resistência ao cisalhamento, Dental ceramics, Zirconia. Silicon, Aging, Shear strength