Oxidation of nickel(II) cyclam and tetraglycine complexes by dissolved oxygen in the presence of sulfur(IV). Synergistic effects of manganese(III) and cobalt(III)

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1999-06-01

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Pezza, Helena Redigolo [UNESP]
Bonifácio, Rodrigo Leandro
Coichev, Nina

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The autoxidation of [Ni(II)(cyclam)]2+ (cyclam = 1,4,8,11- tetraazacyclotetradecane) and Ni(II)tetraglycine, accelerated by S(IV), is studied spectrophotometrically by following the formation of Ni(III) complexes.

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Journal of Chemical Research - Part S, n. 6, p. 347-, 1999.