Coordenaçāo local do Eu(III) em híbridos orgânicos/inorgânicos emissores de luz branca
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Data
2001-07-01
Autores
Carlos, Luís D.
Sá Ferreira, Rute A.
De Zéa Bermudez, Verónica
Bueno, Luciano A. [UNESP]
Molina, Celso [UNESP]
Messaddeq, Younes [UNESP]
Ribeiro, Sidney J. L. [UNESP]
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Resumo
Eu3+ luminescence and EXAFS (Extended X-ray Absorption Fine Structure) results are presented for organic-inorganic hybrid gel hosts composed of a siliceous network to which small chains of oxyethylene units are covalently grafted by means of urea bridges. Coordination numbers for Eu3+ ions range from 12.8 to 9.7 with increasing Eu3+ concentration while the Eu3+-first neighbours mean distance is found to be constant at 2.48-2.49 Å in the same concentration range. Emission spectra display a broad band in the green/blue spectral region superposed to narrow lines appearing in the yellow/red region in such a way that for the eyes emission appears white. The broad band is assigned to intrinsic NH groups emission and also to electron-hole recombination in the nanosised siliceous domains. The narrow lines are assigned to intra-4f6, 5D0→7F0-4 Eu3+ transitions and from the energy position of the 7F0-4 levels a mean distance could be calculated for the Eu3+-first neighbours. The calculated results are in good agreement with the experimental ones obtained from EXAFS analysis.
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EXAFS, Luminescence, Organic-inorganic hybrids
Como citar
Quimica Nova, v. 24, n. 4, p. 453-459, 2001.