Synthesis, spectral and thermal studies on dicarboxylate-bridged palladium(II) coordination polymers. Part II
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Data
2009-07-01
Autores
Fernandes, R. L. [UNESP]
Takahashi, P. M. [UNESP]
Frem, R. C. G. [UNESP]
Netto, A. V. G. [UNESP]
Mauro, A. E.
Matos, J. R.
Título da Revista
ISSN da Revista
Título de Volume
Editor
Springer
Resumo
The synthesis and thermal behavior of the new [Pd(fum)(bipy)] (n) center dot 2nH(2)O (1), [Pd(fum)(bpe)] (n) center dot nH(2)O (2) and [Pd(fum)(pz)] (n) center dot 3nH(2)O (3) {bipy = 4,4'-bipyridine, bpe = 1,2-bis(4-pyridyl)ethene and pz = pyrazine} fumarate complexes are described in this work as well their characterization by IR and (13)C CPMAS NMR spectroscopies. TG curves showed that the compounds released organic ligands and lattice water molecules in the temperature range of 46-491 A degrees C. In all the cases, metallic palladium was identified as the final residue.
Descrição
Palavras-chave
Palladium(II), Fumarate, N-based linear spacers, Thermal studies, Coordination polymers
Como citar
Journal of Thermal Analysis and Calorimetry. Dordrecht: Springer, v. 97, n. 1, p. 153-156, 2009.