Synthesis and characterization of a new platinum(II) complex with L-mimosine
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Data
2005-11-10
Autores
Corbi, P. P.
Massabni, Antonio Carlos [UNESP]
Costa-Neto, C. M.
Título da Revista
ISSN da Revista
Título de Volume
Editor
Taylor & Francis Ltd
Resumo
Synthesis and characterization of a new Pt(II)-mimosine complex are described. Elemental, mass spectrometry and thermal analyses for the complex are consistent with the formula [PtCl2(C8H10N2O4)]center dot 1.5H(2)O. C-13 NMR, N-15 NMR and infrared spectroscopy indicate coordination of the ligand to Pt(II) through the N and O atoms in a square-planar geometry. The final residue after thermal treatment was identified as metallic Pt. The complex is soluble in dimethylsulfoxide.
Descrição
Palavras-chave
platinum(II), L-mimosine, amino acids, metal complex, N-15 NMR
Como citar
Journal of Coordination Chemistry. Abingdon: Taylor & Francis Ltd, v. 58, n. 16, p. 1477-1483, 2005.