Development of an electrochemical sensor based on nanostructured hausmannite-type manganese oxide for detection of sodium ions
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2013-03-25
Autores
Machini, Wesley B.S. [UNESP]
Martin, Cibely S. [UNESP]
Martinez, Murilo T. [UNESP]
Teixeira, Silvio R. [UNESP]
Gomes, Homero M. [UNESP]
Teixeira, Marcos F.S. [UNESP]
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Resumo
The preparation and electrochemical characterization of hausmannite-type manganese oxide to use as a sensing material for sodium ion is described. This paper reports a new via synthetic to obtain of the hausmannite-type manganese oxide and its application in the construction of modified electrode as a voltammetric sensor. The electrochemical activity of hausmannite-type manganese oxide is controlled by intercalation/deintercalation of the sodium ions within the oxide lattice. The detection is based on the measurement of anodic current generated by oxidation of MnIII-MnIV at electrode surface. The best electrochemical response was obtained for a sensor composition of 20% (w/w) hausmannite oxide in the paste, a TRIS buffer solution of pH 6.0-7.0 and a scan rate of 50 mV s-1. A sensitive linear voltammetric response for sodium ions was obtained in the concentration range of 2.01 × 10 -5-2.09 × 10-4 mol L-1 with a slope of 355 μA L mmol-1 and a detection limit of 7.50 × 10 -6 mol L-1 using cyclic voltammetry. The use of hausmannite has significantly improved the selectivity of the sensor compared to the birnessite-type manganese oxide modified electrode. Under the working conditions, the proposed method was successfully applied to determination of sodium ions in urine samples. © 2013 Elsevier B.V.
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Electrochemical sensor, Hausmannite-type manganese oxide, Sensor for sodium ion, Sodium analysis, Urine samples, Electrochemical activities, Electrochemical characterizations, Electrochemical response, Intercalation/deintercalation, Manganese oxide modified, Sodium ions, Urine sample, Voltammetric response, Cyclic voltammetry, Electrochemical sensors, Electrodes, Manganese, Manganese oxide, Metal ions, Oxides, Sensors, Anodic oxidation
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Sensors and Actuators, B: Chemical, v. 181, p. 674-680.