Mono and dinuclear Pd(II) complexes with pyrazole and imidazole-type ligands

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dc.contributor.authorLucca Neto, V. A. [UNESP]
dc.contributor.authorMauro, A. E.
dc.contributor.authorNetto, A. V. G. [UNESP]
dc.contributor.authorMoro, A. C. [UNESP]
dc.contributor.authorNogueira, V. M. [UNESP]
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-20T15:32:31Z
dc.date.available2014-05-20T15:32:31Z
dc.date.issued2009-07-01
dc.description.abstractThe cyanate-bridged cyclopalladated compound [Pd(C(2),N-dmba)(mu-NCO)](2) (dmba=N,N-dimethylbenzylamine) reacts in acetone with pyrazole (pz), 3,5-dimethylpyrazole (dmpz), imidazole (imz) and 2-methylimidazole (mimz) to give [Pd(2)(C(2),N-dmba)(2)(mu-NCO)(mu-pz)] (1), [Pd(2)(C(2),N-dmba)(2)(mu-NCO)(mu-dmpz)] (2), [Pd(C(2),N-dmba)(NCO)(imz)] (3) and [Pd(C(2),N-dmba)(NCO)(mimz)] (4), respectively. The compounds were characterized by elemental analysis, IR spectroscopy and TG. The thermal decomposition of the compounds occurs in three consecutive steps and the final decomposition products were identified as Pd(0) by X-ray powder diffraction. The thermal stability order of the complexes is 2 > 3 > 1 > 4.en
dc.description.affiliationUNESP, São Paulo State Univ, Inst Quim Araraquara, BR-14801970 Araraquara, SP, Brazil
dc.description.affiliationUnespUNESP, São Paulo State Univ, Inst Quim Araraquara, BR-14801970 Araraquara, SP, Brazil
dc.format.extent57-60
dc.identifierhttp://dx.doi.org/10.1007/s10973-008-9667-x
dc.identifier.citationJournal of Thermal Analysis and Calorimetry. Dordrecht: Springer, v. 97, n. 1, p. 57-60, 2009.
dc.identifier.doi10.1007/s10973-008-9667-x
dc.identifier.issn1388-6150
dc.identifier.lattes7927677053650819
dc.identifier.orcid0000-0002-0057-7964
dc.identifier.urihttp://hdl.handle.net/11449/41395
dc.identifier.wosWOS:000270840800010
dc.language.isoeng
dc.publisherSpringer
dc.relation.ispartofJournal of Thermal Analysis and Calorimetry
dc.relation.ispartofjcr2.209
dc.relation.ispartofsjr0,587
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.subjectcyclopalladated compoundsen
dc.subjectimidazolesen
dc.subjectpyrazolesen
dc.subjectspectroscopyen
dc.subjectthermal analysisen
dc.titleMono and dinuclear Pd(II) complexes with pyrazole and imidazole-type ligandsen
dc.typeArtigo
dcterms.licensehttp://www.springer.com/open+access/authors+rights?SGWID=0-176704-12-683201-0
dcterms.rightsHolderSpringer
unesp.author.lattes7927677053650819[3]
unesp.author.lattes3300223970814448[2]
unesp.author.orcid0000-0002-0057-7964[3]

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