Synthesis and structural characterization of dichlorobis (1-phenyl-3-methylpyrazole) palladium(II) and diazidobis (1-phenyl-3-methylpyrazole) palladiium(II)

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dc.contributor.authorNetto, AVG
dc.contributor.authorMauro, A. E.
dc.contributor.authorFrem, RCG
dc.contributor.authorSantana, A. M.
dc.contributor.authorSantos, RHA
dc.contributor.authorZoia, JR
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniversidade de São Paulo (USP)
dc.date.accessioned2014-05-20T15:26:48Z
dc.date.available2014-05-20T15:26:48Z
dc.date.issued2001-01-01
dc.description.abstractMononuclear pyrazolyl Pd(II) complexes of the type [PdX2(phmPz)(2)] (X = Cl-, N-3(-)) have been prepared. The 1-phenyl-3-methylpyrazole displaces acetonitrile from [PdCl2(CH3CN)(2)] to form [PdCl2(PhMPz)(2)] (phmPz = 1-phenyl-3-methylpyrazole) (1). [Pd(N-3)(2)(PhmPz)(2)] (2) could be obtained by metathesis from [PdCl2(CH3CN)(2)] or by substitution of the chloride in (1) by the azide ion. Both complexes were characterized by elemental analysis, infrared spectroscopy, H-1 and C-13 NMR and by single crystal X-ray diffraction. The coordination geometry around Pd(II) in these complexes is nearly square-planar, with the ligands in a trans configuration.en
dc.description.affiliationUNESP, Inst Quim Araraquara, BR-14801970 Araraquara, SP, Brazil
dc.description.affiliationUSP, Inst Quim Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil
dc.description.affiliationUnespUNESP, Inst Quim Araraquara, BR-14801970 Araraquara, SP, Brazil
dc.format.extent129-141
dc.identifierhttp://dx.doi.org/10.1080/00958970108027149
dc.identifier.citationJournal of Coordination Chemistry. Philadelphia: Gordon Breach Publishing, Taylor & Francis Group, v. 54, n. 2, p. 129-141, 2001.
dc.identifier.doi10.1080/00958970108027149
dc.identifier.issn0095-8972
dc.identifier.lattes8534138813417161
dc.identifier.orcid0000-0003-1574-681X
dc.identifier.urihttp://hdl.handle.net/11449/36889
dc.identifier.wosWOS:000170693300004
dc.language.isoeng
dc.publisherGordon Breach Publishing, Taylor & Francis Group
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.ispartofjcr1.703
dc.relation.ispartofsjr0,371
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.subjectpyrazolept
dc.subjectpalladium(II)pt
dc.subjectazidept
dc.subjectinfrared spectroscopypt
dc.subjectNMR spectroscopypt
dc.subjectX-ray diffractionpt
dc.titleSynthesis and structural characterization of dichlorobis (1-phenyl-3-methylpyrazole) palladium(II) and diazidobis (1-phenyl-3-methylpyrazole) palladiium(II)en
dc.typeArtigo
dcterms.licensehttp://journalauthors.tandf.co.uk/permissions/reusingOwnWork.asp
dcterms.rightsHolderGordon Breach Publishing, Taylor & Francis Group
unesp.author.lattes3300223970814448[2]
unesp.author.lattes8534138813417161[3]
unesp.author.orcid0000-0002-0057-7964[1]
unesp.author.orcid0000-0003-1574-681X[3]

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