The investigation of α→β phase transition in poly(vinylidene fluoride) (PVDF)
dc.contributor.author | Constantino, C. J L [UNESP] | |
dc.contributor.author | Job, A. E. [UNESP] | |
dc.contributor.author | Simões, R. D. [UNESP] | |
dc.contributor.author | Giacometti, J. A. [UNESP] | |
dc.contributor.author | Zucolotto, V. | |
dc.contributor.author | Oliveira, O. N. | |
dc.contributor.author | Gozzi, G. [UNESP] | |
dc.contributor.author | Chinaglia, D. L. [UNESP] | |
dc.contributor.institution | Universidade Estadual Paulista (Unesp) | |
dc.contributor.institution | Universidade de São Paulo (USP) | |
dc.date.accessioned | 2014-05-27T11:21:44Z | |
dc.date.available | 2014-05-27T11:21:44Z | |
dc.date.issued | 2005-12-01 | |
dc.description.abstract | The phase transition from the non-polar α-phase to the polar β-phase of poly(vinylidene fluoride) (PVDF) has been investigated using micro-Raman spectroscopy, which is advantageous for being a non-destructive technique. Films of α-PVDF were subjected to stretching under controlled rates and at 80°C, the transition to β-PVDF being monitored by the decrease in the Raman band at 794 cm-1 characteristic of the α-phase, with the concomitant increase in the 839 cm-1 band characteristic of the β-phase. Poling with negative corona discharge was found to affect the a-PVDF morphology improving the Raman bands related to this crystalline phase. This effect is minimized for films stretched to higher ratios. Significantly, corona-induced effects could not be observed with the other experimental techniques, viz. X-ray diffraction and infrared spectroscopy. | en |
dc.description.affiliation | Faculdade de Ciências e Tecnologia UNESP, 19060-900 - Presidente Prudente, SP | |
dc.description.affiliation | Institute de Física de São Carlos USP, 13566-590 - São Carlos, SP | |
dc.description.affiliation | Instituto de Geociências e Ciência Exatas UNESP, 13500-970 - Rio Claro, SP | |
dc.description.affiliationUnesp | Faculdade de Ciências e Tecnologia UNESP, 19060-900 - Presidente Prudente, SP | |
dc.description.affiliationUnesp | Instituto de Geociências e Ciência Exatas UNESP, 13500-970 - Rio Claro, SP | |
dc.format.extent | 178-181 | |
dc.identifier | http://ieeexplore.ieee.org/xpl/abstractAuthors.jsp?arnumber=1612350 | |
dc.identifier.citation | Proceedings - International Symposium on Electrets, v. 2005, p. 178-181. | |
dc.identifier.lattes | 6475585105456744 | |
dc.identifier.scopus | 2-s2.0-33847761025 | |
dc.identifier.uri | http://hdl.handle.net/11449/68617 | |
dc.language.iso | eng | |
dc.relation.ispartof | Proceedings - International Symposium on Electrets | |
dc.rights.accessRights | Acesso aberto | |
dc.source | Scopus | |
dc.subject | Band structure | |
dc.subject | Nondestructive examination | |
dc.subject | Polymer films | |
dc.subject | Raman spectroscopy | |
dc.subject | Vinyl resins | |
dc.subject | X ray diffraction | |
dc.subject | Band characteristics | |
dc.subject | Micro Raman spectroscopy | |
dc.subject | Non polar phases | |
dc.subject | Raman bands | |
dc.subject | Phase transitions | |
dc.title | The investigation of α→β phase transition in poly(vinylidene fluoride) (PVDF) | en |
dc.type | Trabalho apresentado em evento | |
dcterms.license | http://www.ieee.org/publications_standards/publications/rights/rights_policies.html | |
unesp.author.lattes | 6475585105456744[2] | |
unesp.author.lattes | 6118325967319836[1] | |
unesp.author.orcid | 0000-0002-1979-8257[2] | |
unesp.author.orcid | 0000-0002-5921-3161[1] | |
unesp.campus | Universidade Estadual Paulista (Unesp), Faculdade de Ciências e Tecnologia, Presidente Prudente | pt |