A systematic interpretation of the quantum cutting effect by a cooperative energy transfer mechanism in Te4+/Yb3+ co-doped tellurite glasses
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Data
2023-06-01
Autores
Rufino Souza, Ana Kely
Silva, Junior Reis
Costa, Francine Bettio [UNESP]
Silos Moraes, Joao Carlos [UNESP]
Oliveira Nunes, Luiz Antonio de
Cunha Andrade, Luis Humberto da
Lima, Sandro Marcio
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Resumo
The near-infrared downconversion (DC) mechanism in Te4+/Yb3+ co-doped 75TeO2–25Li2O tellurite glasses (amounts in mol%) was closely followed using optical and thermal spectroscopy techniques. The glasses were prepared by the conventional melt-quenching method, with a melting temperature of 800 °C, in an ambient atmosphere, which were the best synthesis conditions for observing Te4+ in the glass. The results indicated that excitation in the ultraviolet region led to an intense emission of two NIR photons (at around 978 nm) in the co-doped tellurite glasses. This effect revealed the occurrence of a cooperative energy transfer (CET) mechanism in the system, where a Te4+ ion was responsible for the excitation of two Yb3+ ions. The CET efficiency (ηCET) was calculated from the Te4+ lifetime, obtaining a maximum of 74% for the tellurite glass prepared with the highest Yb3+ concentration. The use of thermal lens spectroscopy confirmed the quantum cutting effect, by observing the dependence of the thermal properties of the glass on the Yb3+ concentration. A maximum DC efficiency of 137% was measured for the sample with 4 mol% of Yb3+.
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Cooperative energy transfer, Downconversion, Fluorescence quantum efficiency, Quantum cutting, Te4+ ion, Tellurite glass, Thermal lens spectroscopy, Yb3+ ion
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Ceramics International, v. 49, n. 11, p. 19470-19480, 2023.