Influence of pH of Colloidal Suspension on the Electrical Conductivity of SnO2 thin Films Deposited Via Sol-Gel-Dip-Coating

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dc.contributor.authorRavaro, Leandro Piaggi [UNESP]
dc.contributor.authorScalvi, Luis Vicente de Andrade [UNESP]
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-20T13:26:19Z
dc.date.available2014-05-20T13:26:19Z
dc.date.issued2011-01-01
dc.description.abstractTin dioxide (SnO2) thin films are deposited by the dip-coating technique from colloidal suspensions prepared with distinct pH through the sol-gel method. The decrease of the pH contributes to the destruction of an electrical layer adjacent to particles in solution, leading to a high degree of aggregation among these particles due to the generation of cross-linked bonds (Sn-O-Sn) between them. The aggregation affects the electrical properties of films, because the pH variation produces particle with distinct sizes in the film. Undoped samples prepared from pH 6 leads to the highest conductivity among the investigated undoped samples, in agreement with X-ray diffractograms, which indicate higher crystallinity for lower pH. Arrhenius plot evaluated from temperature dependent conductivity data leads to activation energies of the deepest level between 67 to 140 meV, for the films prepared from suspensions with pH 6 to 11. The most probable explanation for this variation in the conductivity and activation energy is related to distinct potential barriers between grains, due to distinct packing caused by cross-linked bonds formed during suspension phase. Characterization of samples lightly doped with Er3+ confirms that acid pH leads to higher conductivity, but the highest conduction takes place at even lower pH when compared to undoped thin films.en
dc.description.affiliationUNESP State Univ São Paulo, Postgrad Program Mat Sci & Technol, Bauru, SP, Brazil
dc.description.affiliationUNESP State Univ São Paulo, Dept Phys, Bauru, SP, Brazil
dc.description.affiliationUnespUNESP State Univ São Paulo, Postgrad Program Mat Sci & Technol, Bauru, SP, Brazil
dc.description.affiliationUnespUNESP State Univ São Paulo, Dept Phys, Bauru, SP, Brazil
dc.description.sponsorshipCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.format.extent113-117
dc.identifierhttp://dx.doi.org/10.1590/S1516-14392011005000010
dc.identifier.citationMaterials Research-ibero-american Journal of Materials. São Carlos: Universidade Federal de São Carlos (UFSCar), Dept Engenharia Materials, v. 14, n. 1, p. 113-117, 2011.
dc.identifier.doi10.1590/S1516-14392011005000010
dc.identifier.fileS1516-14392011000100019.pdf
dc.identifier.issn1516-1439
dc.identifier.lattes7730719476451232
dc.identifier.orcid0000-0001-5762-6424
dc.identifier.scieloS1516-14392011000100019
dc.identifier.urihttp://hdl.handle.net/11449/8459
dc.identifier.wosWOS:000289856400019
dc.language.isoeng
dc.publisherUniversidade Federal de São Carlos (UFSCar), Dept Engenharia Materials
dc.relation.ispartofMaterials Research-ibero-american Journal of Materials
dc.relation.ispartofjcr1.103
dc.relation.ispartofsjr0,398
dc.rights.accessRightsAcesso aberto
dc.sourceWeb of Science
dc.subjecttin dioxideen
dc.subjectsol-gel-dip-coatingen
dc.subjectelectrical conductivityen
dc.subjectpHen
dc.titleInfluence of pH of Colloidal Suspension on the Electrical Conductivity of SnO2 thin Films Deposited Via Sol-Gel-Dip-Coatingen
dc.typeArtigo
dcterms.licensehttp://www.scielo.br/revistas/mr/paboutj.htm
dcterms.rightsHolderUniversidade Federal de São Carlos (UFSCar), Dept Engenharia Materials
unesp.author.lattes7730719476451232[2]
unesp.author.orcid0000-0001-5762-6424[2]
unesp.author.orcid0000-0002-4932-5776[1]
unesp.campusUniversidade Estadual Paulista (Unesp), Faculdade de Ciências, Baurupt
unesp.departmentFísica - FCpt

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