Fe2V4O13 photoanode material: an interesting approach to non-enzymatic glucose oxidation
| dc.contributor.author | da Silva Pelissari, Marcelo Rodrigues [UNESP] | |
| dc.contributor.author | Camargo, Luan Pereira | |
| dc.contributor.author | da Silva, Paulo Rogério Catarini | |
| dc.contributor.author | Dall’Antonia, Luiz Henrique | |
| dc.contributor.institution | Universidade Estadual Paulista (UNESP) | |
| dc.contributor.institution | Universidade Estadual de Londrina (UEL) | |
| dc.date.accessioned | 2022-04-28T19:52:55Z | |
| dc.date.available | 2022-04-28T19:52:55Z | |
| dc.date.issued | 2022-01-01 | |
| dc.description.abstract | The use of non-enzymatic material for the electrooxidation reaction of glucose is still a challenge to be overcome since these materials must have high sensitivity to glucose, high chemical stability and, if possible, be obtained quickly and with a low-cost process. In this context, iron vanadate (Fe2V4O13) was successfully synthesized using the easy and low-cost Successive Ionic Layer Adsorption and Reaction process and used as an interesting non-enzymatic photoanode material approach for the photoelectrochemical oxidation reaction of glucose. From the X-ray diffraction and Raman measurements, it was possible to observe that the monoclinic crystalline phase Fe2V4O13 was formed at 500 °C, without any secondary phases. The electrochemical characterization, performed by linear sweep voltammetry (LSV), chronoamperometry and electrochemical impedance spectroscopy techniques, under light condition, showed the remarkable photoelectrochemical activity of the FTO/Fe2V4O13 electrode, such as a high photocurrent density at + 0.6 V vs. Ag/AgCl (0.2 mA cm−2); good reproducibility under transient light condition; low charge transfer resistance; and flat band potential consistent with the LSV and typical value of this material (+ 0.45 V). The performance of the electrode as non-enzymatic glucose interaction, carried out by chronoamperometry technique, showed a remarkable performance in the photoelectrooxidation reaction of glucose, with linear behavior (R2 = 0.9975) of the analytical curve (glucose concentration from 0 to 10 mmol L−1), excellent reproducibility, a slight loss in photoelectrochemical signal after five successive reading cycles, good sensitivity (0.370 μA mM−1 cm−2) and limit of detection (52 µmol L–1). Besides, the analysis of interference species showed good electrode selectivity. Graphical abstract: Fe2V2O13 photoelectrode obtained by the Successive Ionic Layer Adsorption and Reaction (SILAR) process, and its use for glucose photoelectrocatalytic oxidation reaction [Figure not available: see fulltext.] | en |
| dc.description.affiliation | Faculdade de Engenharia CTI UNESP – Universidade Estadual Paulista, SP | |
| dc.description.affiliation | Departamento de Química/CCE/UEL UEL – Universidade Estadual de Londrina, CP 10.011, PR | |
| dc.description.affiliation | Departamento de Física UEL – Universidade Estadual de Londrina, PR | |
| dc.description.affiliationUnesp | Faculdade de Engenharia CTI UNESP – Universidade Estadual Paulista, SP | |
| dc.identifier | http://dx.doi.org/10.1007/s10853-022-07093-z | |
| dc.identifier.citation | Journal of Materials Science. | |
| dc.identifier.doi | 10.1007/s10853-022-07093-z | |
| dc.identifier.issn | 1573-4803 | |
| dc.identifier.issn | 0022-2461 | |
| dc.identifier.scopus | 2-s2.0-85127598702 | |
| dc.identifier.uri | http://hdl.handle.net/11449/223765 | |
| dc.language.iso | eng | |
| dc.relation.ispartof | Journal of Materials Science | |
| dc.source | Scopus | |
| dc.title | Fe2V4O13 photoanode material: an interesting approach to non-enzymatic glucose oxidation | en |
| dc.type | Artigo | |
| unesp.author.orcid | 0000-0003-1883-0363[4] |