SAXS study of formation and growth of tin oxide nanoparticles in the presence of complexing ligands

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dc.contributor.authorBroussous, L.
dc.contributor.authorSantilli, Celso Valentim [UNESP]
dc.contributor.authorPulcinelli, Sandra Helena [UNESP]
dc.contributor.authorCraievich, A. F.
dc.contributor.institutionENSCM
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniversidade de São Paulo (USP)
dc.date.accessioned2014-05-20T15:24:09Z
dc.date.available2014-05-20T15:24:09Z
dc.date.issued2002-03-21
dc.description.abstractThe effect of acetylacetone (acac) complexing ligand on the formation and growth of tin oxide-based nanoparticles during thermohydrolysis at 70 degreesC of a tin precursor SnCl4-n(acac)(n) (0 less than or equal to n less than or equal to 2) solution was analyzed by in situ small-angle X-ray scattering. A. transparent and stable sol was obtained after 2 h of thermohydrolysis at 70 degreesC, allowing the quantitative determination of the particle volume distribution function and its variation with the reaction time. The number of colloidal particles for equivalent thermohydrolysis temperature and time decreases as the [acac]/[Sn] ratio in initial solution increases from 0.5 to 6. Instead, the amount of soluble species remaining in solution increases for increasing [acac]/[Sn] ratio within the same range. This indicates that increasing amounts of Sn-acetylacetone complexes partially prevent the hydrolysis and consequent formation of colloidal particles. The N-2 adsorption isotherm characterization of freeze-dried powders demonstrates that the average pore size is approximately equal to the average size (approximate to9 Angstrom) of the colloidal primary particles in the sol, and that the porosity and surface area (approximate to200 m(2) g(-1)) are independent of the acac content in the initial solution.en
dc.description.affiliationENSCM, Lab Mat & Proc Membranaires, F-34296 Montpellier, France
dc.description.affiliationUNESP, Inst Quim, BR-14800900 Araraquara, SP, Brazil
dc.description.affiliationUSP, Inst Fis, BR-05315970 São Paulo, SP, Brazil
dc.description.affiliationUnespUNESP, Inst Quim, BR-14800900 Araraquara, SP, Brazil
dc.format.extent2855-2860
dc.identifierhttp://dx.doi.org/10.1021/jp012700b
dc.identifier.citationJournal of Physical Chemistry B. Washington: Amer Chemical Soc, v. 106, n. 11, p. 2855-2860, 2002.
dc.identifier.doi10.1021/jp012700b
dc.identifier.issn1520-6106
dc.identifier.lattes5584298681870865
dc.identifier.lattes9971202585286967
dc.identifier.orcid0000-0002-8356-8093
dc.identifier.urihttp://hdl.handle.net/11449/34800
dc.identifier.wosWOS:000174551500008
dc.language.isoeng
dc.publisherAmer Chemical Soc
dc.relation.ispartofJournal of Physical Chemistry B
dc.relation.ispartofjcr3.146
dc.relation.ispartofsjr1,331
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.titleSAXS study of formation and growth of tin oxide nanoparticles in the presence of complexing ligandsen
dc.typeArtigo
dcterms.licensehttp://pubs.acs.org/paragonplus/copyright/jpa_form_a.pdf
dcterms.rightsHolderAmer Chemical Soc
unesp.author.lattes9971202585286967
unesp.author.lattes5584298681870865[2]
unesp.author.orcid0000-0002-8356-8093[2]
unesp.campusUniversidade Estadual Paulista (Unesp), Instituto de Química, Araraquarapt

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Artigos - Físico Química - IQ