Compostos heterometálicos. Interação do tricarbonil com ligação W-Hg, [WCl(CO)3(bipy)(HgCl)], com tiouréias

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dc.contributor.authorMuraoka, T. K.
dc.contributor.authorMauro, Antonio Eduardo [UNESP]
dc.contributor.authorNogueira, Vânia Martins [UNESP]
dc.contributor.authorHaddad, P. S.
dc.contributor.institutionFederacao Fac Isoladas Araraquara
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-20T15:22:38Z
dc.date.available2014-05-20T15:22:38Z
dc.date.issued1997-01-01
dc.description.abstractReactions of [WC1(CO)(3)(bipy)(HgCl)], [bipy = 2,2 -bipyridine], with thioureas were performed giving compounds of the type [WCl(CO)(3)(bipy)(HgCl)L], [L = thiourea (tu); N-methylthiourea (mtu); N,N-dimethyithiourea (dmtu)] in which the coordination sphere of the tungsten atom remained unchanged. The coordination of the thioureas to mercury atom was proved to occur in accord to infrared spectra, through the sulphur atom.en
dc.description.affiliationFederacao Fac Isoladas Araraquara, FEFIARA, BR-24802320 Araraquara, SP, Brazil
dc.description.affiliationUNESP, Inst Quim, Dept Quim Geral & Inorgan, BR-14800900 Araraquara, SP, Brazil
dc.description.affiliationUnespUNESP, Inst Quim, Dept Quim Geral & Inorgan, BR-14800900 Araraquara, SP, Brazil
dc.format.extent75-82
dc.identifierhttp://dx.doi.org/10.1590/S0100-46701997000100007
dc.identifier.citationEcletica Química. São Paulo: Editora Unesp, v. 22, p. 75-82, 1997.
dc.identifier.doi10.1590/S0100-46701997000100007
dc.identifier.issn0100-4670
dc.identifier.lattes3300223970814448
dc.identifier.lattes8980849254118153
dc.identifier.scieloS0100-46701997000100007
dc.identifier.urihttp://hdl.handle.net/11449/33587
dc.identifier.wosWOS:000074572200007
dc.language.isopor
dc.publisherEditora Unesp
dc.relation.ispartofEclética Química
dc.rights.accessRightsAcesso aberto
dc.sourceWeb of Science
dc.subjectheterometallicpt
dc.subjecttricarbonylpt
dc.subjectthioureapt
dc.subjectinfrared spectroscopypt
dc.titleCompostos heterometálicos. Interação do tricarbonil com ligação W-Hg, [WCl(CO)3(bipy)(HgCl)], com tiouréiaspt
dc.title.alternativeHeterometallic compounds. Interaction of the tricarbonyl containing W-Hg bond, [WCl(CO)(3)(bipy)(HgCl)], with thioureas.en
dc.typeArtigo
dcterms.licensehttp://www.scielo.br/revistas/eq/paboutj.htm
dcterms.rightsHolderEditora Unesp
unesp.author.lattes3300223970814448[2]
unesp.author.lattes8980849254118153
unesp.campusUniversidade Estadual Paulista (Unesp), Instituto de Química, Araraquarapt

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Artigos - Química Inorgânica - IQ