An efficient and versatile synthesis of acylpolyamine spider toxins
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Elsevier B.V.
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Abstract
An efficient and versatile synthesis of acylpolyamine spider toxins was developed based on the structural classification of the Nephila and Nephilengys spider toxins using the 2-nitrobenzenesulfonamide protecting group. The naturally occurring toxins 1-5 representing each structural type have been efficiently synthesized by this method in a high overall yield with few steps. (C) 2002 Elsevier B.V. Ltd. All rights reserved.
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Bioorganic & Medicinal Chemistry Letters. Oxford: Pergamon-Elsevier B.V., v. 12, n. 3, p. 299-302, 2002.
