Raman scattering study of the PbZr1-xTixO3 system: Rhombohedral-monoclinic-tetragonal phase transitions
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In this paper we present a Raman-scattering study of the phase transitions in the PbZr1-xTixO3 systems around the morphotropic phase boundary over a wide temperature range. The boundary between rhombohedral and monoclinic phases was found to be a quasivertical line between x = 0.46 and x = 0.47. We also studied the monoclinic-tetragonal phase boundary and our spectroscopic results agree very well with those reported by using x-ray diffraction.
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Physical Review B - Condensed Matter and Materials Physics, v. 66, n. 13, p. 1321071-1321074, 2002.
