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CONTRIBUTION TO THE STUDY OF ZIRCONIUM AND HAFNIUM ALPHA-HYDROXYCARBOXYLATES

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Authors

Barbieri, R. S.

Terra, V. R.

Netto, A. M.

Rocha, J. C.

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Coadvisor

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Undergraduate course

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Volume Title

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Soc Brasileira Quimica

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Article

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Acesso abertoAcesso Aberto

Abstract

A study of both zirconium and hafnium alpha-hydroxycarboxylates for analytical applications is presented, These compounds are studied by infrared spectroscopy, thermal analysis and X-ray diffractometry. dl-Mandelic, dl-p-bromomandelic and dl-2-naphthylglycolic acids are the more adequate reagents for gravimetric determinations of zirconium and hafnium, the ligands dl-2-hydroxyhexanoic and dl-2-hydroxydodecanoic acids were used for the first time and the results showed that they are also adequate reagents for the same purpose.

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Language

English

Citation

Quimica Nova. São Paulo: Soc Brasileira Quimica, v. 18, n. 1, p. 40-43, 1995.

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