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A three-dimensional network constructed from the assembly of 1,3-diaminopropane-copper(II) and tetracyanopalladate(II) moieties

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dc.contributor.authorLegendre, Alexandre de Oliveira [UNESP]
dc.contributor.authorMauro, Antonio Eduardo [UNESP]
dc.contributor.authorRodrigues de Oliveira, Milene Aparecida
dc.contributor.authordo Prado Gambardella, Maria Teresa
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniversidade de São Paulo (USP)
dc.date.accessioned2014-05-20T13:26:58Z
dc.date.available2014-05-20T13:26:58Z
dc.date.issued2008-08-01
dc.description.abstractThe coordination polymer [Cu(Pd(CN)(4))(pn)](n) (pn = 1,3-diaminopropane) has been synthesized and characterized by elemental analysis, infrared spectroscopy and single-crystal X-ray diffraction. The crystal structure showed that three cyano groups of each [Pd(CN)(4)] unit bridge Cu(II) centers leading to the formation of a three-dimensional network. A series of bifurcated hydrogen bonds between the amino groups of the diamine and the nonbridging cyano groups of the cyanometallate result in the organization of suprarnolecular chains and rings along the polymer. (c) 2008 Elsevier B.V. All rights reserved.en
dc.description.affiliationSão Paulo State Univ UNESP, Inst Quim Araraquara, BR-14800900 Araraquara, SP, Brazil
dc.description.affiliationUniv São Paulo, Inst Quim São Carlos, BR-13560970 São Carlos, SP, Brazil
dc.description.affiliationUnespSão Paulo State Univ UNESP, Inst Quim Araraquara, BR-14800900 Araraquara, SP, Brazil
dc.format.extent896-898
dc.identifierhttp://dx.doi.org/10.1016/j.inoche.2008.04.031
dc.identifier.citationInorganic Chemistry Communications. Amsterdam: Elsevier B.V., v. 11, n. 8, p. 896-898, 2008.
dc.identifier.doi10.1016/j.inoche.2008.04.031
dc.identifier.issn1387-7003
dc.identifier.lattes3300223970814448
dc.identifier.urihttp://hdl.handle.net/11449/8774
dc.identifier.wosWOS:000258215600021
dc.language.isoeng
dc.publisherElsevier B.V.
dc.relation.ispartofInorganic Chemistry Communications
dc.relation.ispartofjcr1.810
dc.relation.ispartofsjr0,430
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.subjectcopper(II)en
dc.subjectcoordination polymersen
dc.subjecttetracyanopalladate(II)en
dc.subject1,3-diaminopropaneen
dc.subjectsupramolecular chemistryen
dc.subjecthydrogen bondsen
dc.titleA three-dimensional network constructed from the assembly of 1,3-diaminopropane-copper(II) and tetracyanopalladate(II) moietiesen
dc.typeArtigo
dcterms.licensehttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dcterms.rightsHolderElsevier B.V.
dspace.entity.typePublication
unesp.author.lattes3300223970814448[2]
unesp.author.lattes3123518117881050[1]
unesp.author.orcid0000-0002-2794-5763[1]
unesp.campusUniversidade Estadual Paulista (UNESP), Instituto de Química, Araraquarapt
unesp.departmentQuímica Inorgânica - IQARpt

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Araraquara - IQAR - Instituto de Química