Reactivity of towards copper (I) compounds: Synthesis of binuclear heteromettalic species having CS2 bridging Fe(O) and Cu(I)
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Abstract
This work describes the one pot syntheses and characterization of two new heterometallic carbonyl compounds of the type [Fe(CO)3(m-CS2)(PPh3)(CuX)], X = Cl, ClO4. Both compounds were investigated by infrared and 31P{1H} NMR spectroscopies in order to clarify the coordination mode of the carbonyl groups, as well the bridging disposition of the carbon disulfide between iron (0) and copper (I) atoms.
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Portuguese
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Ecletica Quimica, v. 32, n. 2, p. 7-11, 2007.
