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A comparative study of hydrosilane compounds as cocatalysts in the metathesis of 1-hexene

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dc.contributor.authorBaibich, I. M.
dc.contributor.authorKern, C.
dc.contributor.authordos Santos, JHZ
dc.contributor.institutionUniversidade Federal do Rio Grande do Sul (UFRGS)
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-20T15:21:36Z
dc.date.available2014-05-20T15:21:36Z
dc.date.issued1998-12-21
dc.description.abstractThe selectivity of I-hexene metathesis using WCI6 as catalyst was evaluated with a series of hydrosilane-compounds as cocatalysts: Ph3SiH, Ph2SiH2, PhSiH3 and polymethylhydrosiloxane (PMHS). The metathesis reaction is favored by the addition of promoters. When in the presence of WCl4(OAr)(2), OAr = 2,6-dichlorophenoxide, 2,6-difluorophenoxide, olefin metathesis occurs with good selectivity without the use of promoters. (C) 1998 Elsevier B.V. B.V. All rights reserved.en
dc.description.affiliationUniv Fed Rio Grande Sul, Inst Quim, BR-91501970 Porto Alegre, RS, Brazil
dc.description.affiliationUniv Estadual Paulista, Inst Quim, BR-14800900 Araraquara, SP, Brazil
dc.description.affiliationUnespUniv Estadual Paulista, Inst Quim, BR-14800900 Araraquara, SP, Brazil
dc.format.extent213-217
dc.identifierhttp://dx.doi.org/10.1016/S1381-1169(98)00076-4
dc.identifier.citationJournal of Molecular Catalysis A-chemical. Amsterdam: Elsevier B.V., v. 136, n. 3, p. 213-217, 1998.
dc.identifier.doi10.1016/S1381-1169(98)00076-4
dc.identifier.issn1381-1169
dc.identifier.urihttp://hdl.handle.net/11449/32729
dc.identifier.wosWOS:000077201700001
dc.language.isoeng
dc.publisherElsevier B.V.
dc.relation.ispartofJournal of Molecular Catalysis A: Chemical
dc.relation.ispartofjcr4.397
dc.rights.accessRightsAcesso restritopt
dc.sourceWeb of Science
dc.subjecttungsten catalystpt
dc.subjecthydrosilane cocatalystspt
dc.subject1-hexene metathesispt
dc.titleA comparative study of hydrosilane compounds as cocatalysts in the metathesis of 1-hexeneen
dc.typeArtigopt
dcterms.licensehttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dcterms.rightsHolderElsevier B.V.
dspace.entity.typePublication
relation.isOrgUnitOfPublicationbc74a1ce-4c4c-4dad-8378-83962d76c4fd
relation.isOrgUnitOfPublication.latestForDiscoverybc74a1ce-4c4c-4dad-8378-83962d76c4fd
unesp.campusUniversidade Estadual Paulista (UNESP), Instituto de Química, Araraquarapt

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