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Synthesis, Infrared Spectroscopy and Crystal Structure Determination of a New Decavanadate

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dc.contributor.authorGuilherme, Luciana Rebelo [UNESP]
dc.contributor.authorMassabni, Antonio Carlos [UNESP]
dc.contributor.authorDametto, Alessandra Cristina [UNESP]
dc.contributor.authorCorrea, Rodrigo de Souza
dc.contributor.authorde Araujo, Alexandre Suman
dc.contributor.institutionUniversidade de São Paulo (USP)
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-20T14:02:39Z
dc.date.available2014-05-20T14:02:39Z
dc.date.issued2010-11-01
dc.description.abstractSynthesis, infrared spectroscopy and crystal structure of a new potassium decavanadate decahydrate, K-6[V10O28] 10H(2)O, has been reported The infrared spectrum is dominated by decavanadate polyanion and water bands The X-ray crystallography analysis found the compound crystallizes in a triclinic system with the parameters a = 10 5334 (4) angstrom, b = 10 6600 (4) angstrom, c = 17 7351 (5) angstrom, alpha = 76 940 (2)degrees, beta = 75 836 (2)degrees, gamma = 64 776 (2)degrees, V = 1,729 86 (11) A(3), Z = 2, space group P (1) over bar The polyanion consists of ten [VO6] octahedra sharing edges, in which the V-O distances are in good agreement with those reported for other decavanadates The crystal structure is stabilized by potassium cations and water molecules forming a complex pattern of hydrogen bonding and short contact ionic interactionsen
dc.description.affiliationUniv São Paulo, Inst Fis São Carlos, São Carlos, SP, Brazil
dc.description.affiliationUniv Estadual Paulista, Inst Quim Araraquara, Araraquara, SP, Brazil
dc.description.affiliationUnespUniv Estadual Paulista, Inst Quim Araraquara, Araraquara, SP, Brazil
dc.description.sponsorshipCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.format.extent897-901
dc.identifierhttp://dx.doi.org/10.1007/s10870-010-9759-x
dc.identifier.citationJournal of Chemical Crystallography. New York: Springer/plenum Publishers, v. 40, n. 11, p. 897-901, 2010.
dc.identifier.doi10.1007/s10870-010-9759-x
dc.identifier.issn1074-1542
dc.identifier.urihttp://hdl.handle.net/11449/22087
dc.identifier.wosWOS:000284078600001
dc.language.isoeng
dc.publisherSpringer/plenum Publishers
dc.relation.ispartofJournal of Chemical Crystallography
dc.relation.ispartofjcr0.699
dc.relation.ispartofsjr0,209
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.subjectPotassium decavanadate decahydrateen
dc.subjectInfrared spectrumen
dc.subjectCrystal structureen
dc.subjectMolecular interactionen
dc.titleSynthesis, Infrared Spectroscopy and Crystal Structure Determination of a New Decavanadateen
dc.typeArtigo
dcterms.licensehttp://www.springer.com/open+access/authors+rights?SGWID=0-176704-12-683201-0
dcterms.rightsHolderSpringer/plenum Publishers
dspace.entity.typePublication
unesp.author.lattes2044157599722078[5]
unesp.author.orcid0000-0001-9376-9748[5]
unesp.campusUniversidade Estadual Paulista (UNESP), Instituto de Química, Araraquarapt
unesp.departmentQuímica Inorgânica - IQARpt

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Araraquara - IQAR - Instituto de Química