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Structural and Spectroscopic Studies of Pr3+-Doped GdAlO3

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Institute of Electrical and Electronics Engineers (IEEE)

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Letter

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Abstract

In this work, GdAlO3:Pr3+ was successfully prepared by the Pechini method at lower temperatures when compared to others methods such as solid-state synthesis and sol-gel process. In accordance to the XRD data, the fully crystalline single-phase GdAlO3 could be obtained at 900 degrees C. Luminescence measurements indicate Gd -> Pr3+ energy transfer. In the emission spectra, the P-3(0) ->(3) H-4 (blue emission) and D-1(2) ->(3) H-4 (red emission) transitions of Pr3+ ions can be observed and the ratio between their intensities depends on the Pr3+ content due to the cross-relaxation phenomenon.

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Gadolinium compounds, luminescence, praseodymium, scintillation detectors

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English

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IEEE Transactions on Nuclear Science. Piscataway: IEEE-Inst Electrical Electronics Engineers Inc, v. 57, n. 3, p. 1260-1263, 2010.

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Instituto de Química
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Campus: Araraquara


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