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REDUCTION OF THE AMIDO-BONDED (2-PICOLINAMIDO)PENTAAMMINERUTHENIUM(III) FOLLOWED BY FORMATION OF CIS-(2-PICOLINAMIDE)TETRAAMMINERUTHENIUM(II)

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dc.contributor.authorDarocha, Z. N.
dc.contributor.authorChiericato, G.
dc.contributor.authorTfouni, E.
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniversidade de São Paulo (USP)
dc.date.accessioned2014-05-20T15:29:21Z
dc.date.available2014-05-20T15:29:21Z
dc.date.issued1994-10-12
dc.description.abstract[(NH3)(5)Ru-III(2-NCpy)], obtained from electrochemical oxidation of the Ru(II) complex, undergoes hydrolysis to the amido-bonded [Ru-III(NHC(O)-2-py)]. The electrochemical reduction of this latter complex to Ru(II) is followed by an aquation reaction to form [R(II)(NH3)(5)(OH2)] and free picolinamide and a chelation reaction to form cis-[R(II)-(NH3)(4)(2-pica)] with the displacement of one cis ammonia.en
dc.description.affiliationUNESP,INST QUIM ARARAQUARA,ARARAQUARA,SP,BRAZIL
dc.description.affiliationUNIV SAO PAULO,FAC FILOSOFIA CIENCIAS & LETRAS RIBEIRAO PRET,BR-14040901 RIBEIRAO PRET,SP,BRAZIL
dc.description.affiliationUnespUNESP,INST QUIM ARARAQUARA,ARARAQUARA,SP,BRAZIL
dc.format.extent4619-4620
dc.identifier.citationInorganic Chemistry. Washington: Amer Chemical Soc, v. 33, n. 21, p. 4619-4620, 1994.
dc.identifier.issn0020-1669
dc.identifier.urihttp://hdl.handle.net/11449/38953
dc.identifier.wosWOS:A1994PM68500007
dc.language.isoeng
dc.publisherAmer Chemical Soc
dc.relation.ispartofInorganic Chemistry
dc.relation.ispartofjcr4.700
dc.relation.ispartofsjr1,892
dc.rights.accessRightsAcesso restritopt
dc.sourceWeb of Science
dc.titleREDUCTION OF THE AMIDO-BONDED (2-PICOLINAMIDO)PENTAAMMINERUTHENIUM(III) FOLLOWED BY FORMATION OF CIS-(2-PICOLINAMIDE)TETRAAMMINERUTHENIUM(II)en
dc.typeArtigopt
dcterms.licensehttp://pubs.acs.org/paragonplus/copyright/jpa_form_a.pdf
dcterms.rightsHolderAmer Chemical Soc
dspace.entity.typePublication
unesp.campusUniversidade Estadual Paulista (UNESP), Instituto de Química, Araraquarapt

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Araraquara - IQAR - Instituto de Química