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Molecular and crystal structure of Di(μ-N,S-thiocyanato)-bis[(N,N-dimethylbenzylamine-C2, N)palladium(II)]

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dc.contributor.authorMauro, Antonio Eduardo [UNESP]
dc.contributor.authorNetto, Adelino V.G. [UNESP]
dc.contributor.authorMoro, Antonio C. [UNESP]
dc.contributor.authorFerreira, Janaina G. [UNESP]
dc.contributor.authorSantos, Regina H.A.
dc.contributor.authorde Almeida, Eduardo T.
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniversidade de São Paulo (USP)
dc.date.accessioned2014-05-27T11:23:54Z
dc.date.available2014-05-27T11:23:54Z
dc.date.issued2009-05-01
dc.description.abstractThe cyclopalladated complex [Pd(C2,N-dmba)(μ-SCN)]2, where dmba = N,N-dimethylbenzylamine, was structurally characterized by single-crystal X-ray diffraction. This compound crystallizes in the monoclinic system, space group P21/n with a = 9.578(1)Å, b = 12.323(2)Å, c = 10.279(2)Å, β = 117.03(1)°, V = 1080.7(3)Å3, Z = 2. Each Pd(II) center displays a distorted square-planar coordination environment, formed by the C and N atoms from the dmba ligand, and one set of N and S atoms from the bridging SCN groups. 2009 © The Japan Society for Analytical Chemistry.en
dc.description.affiliationDepartamento de Química Geral e Inorgânica Instituto de Química de Araraquara-UNESP, C. P. 355, CEP 14801-970, Araraquara, S. P.
dc.description.affiliationDepartamento de Química e Física Molecular Instituto de Química-USP, C. P. 780, CEP 13560-970, São Carlos, S. P.
dc.description.affiliationDepartamento de Ciências Exatas-UNIFAL, CEP 37130-000, Alfenas, M. G.
dc.description.affiliationUnespDepartamento de Química Geral e Inorgânica Instituto de Química de Araraquara-UNESP, C. P. 355, CEP 14801-970, Araraquara, S. P.
dc.format.extent65-66
dc.identifierhttp://dx.doi.org/10.2116/xraystruct.25.65
dc.identifier.citationX-ray Structure Analysis Online, v. 25, n. 5, p. 65-66, 2009.
dc.identifier.doi10.2116/xraystruct.25.65
dc.identifier.file2-s2.0-73249123048.pdf
dc.identifier.issn1883-3578
dc.identifier.lattes3300223970814448
dc.identifier.lattes7927677053650819
dc.identifier.orcid0000-0002-0057-7964
dc.identifier.scopus2-s2.0-73249123048
dc.identifier.urihttp://hdl.handle.net/11449/70994
dc.language.isoeng
dc.relation.ispartofX-ray Structure Analysis Online
dc.relation.ispartofsjr0,175
dc.rights.accessRightsAcesso aberto
dc.sourceScopus
dc.titleMolecular and crystal structure of Di(μ-N,S-thiocyanato)-bis[(N,N-dimethylbenzylamine-C2, N)palladium(II)]en
dc.typeNota
dcterms.licensehttps://www.jstage.jst.go.jp/pub/html/AY04S120_en.html
dspace.entity.typePublication
unesp.author.lattes3300223970814448[1]
unesp.author.lattes7927677053650819[2]
unesp.author.orcid0000-0002-0057-7964[2]
unesp.campusUniversidade Estadual Paulista (UNESP), Instituto de Química, Araraquarapt
unesp.departmentQuímica Inorgânica - IQARpt

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