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Self-assembly of cyclometallated Pd(II) compounds directed by C-H center dot center dot center dot pi interactions: A structural evidence for metalloaromaticity in a cyclopalladated ring

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dc.contributor.authorSantana, Anderson M. [UNESP]
dc.contributor.authorFerreira, Janaina G. [UNESP]
dc.contributor.authorMoro, Antonio C. [UNESP]
dc.contributor.authorLemos, Sahra C. [UNESP]
dc.contributor.authorMauro, Antonio Eduardo [UNESP]
dc.contributor.authorNetto, Adelino Vieira de Godoy [UNESP]
dc.contributor.authorFrem, Regina Célia Galvão [UNESP]
dc.contributor.authorSantos, Regina H. A.
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniversidade Federal de Mato Grosso (UFMT)
dc.contributor.institutionUniversidade de São Paulo (USP)
dc.date.accessioned2014-05-20T14:20:03Z
dc.date.available2014-05-20T14:20:03Z
dc.date.issued2011-01-01
dc.description.abstractStructural studies on the two binuclear cyclometallated compounds [Pd(C-2,N-bzan)(mu-N-3)](2) (1) and [Pd(C-2,N-bzan)(mu-Pz)](2) (2) (bzan = N-benzylideneaniline) have been carried out in this work. In both compounds, C-H center dot center dot center dot pi interactions play an important role in the molecular self-assembly. In complex 1, ortho-CH bonds from bzan moiety interact with the cyclopalladated ring at a distance of C-bzan center dot center dot center dot C-g 3.448(6) angstrom, providing a new structural evidence for the metalloaromaticity of the cyclometallated ring. (C) 2010 Elsevier B.V. All rights reserved.en
dc.description.affiliationUNESP Univ Estadual Paulista, Inst Quim Araraquara, BR-14801970 Araraquara, SP, Brazil
dc.description.affiliationICET UFMT, BR-78060900 Cuiaba, MT, Brazil
dc.description.affiliationUniv São Paulo, Inst Quim São Carlos, BR-13560970 São Carlos, SP, Brazil
dc.description.affiliationUnespUNESP Univ Estadual Paulista, Inst Quim Araraquara, BR-14801970 Araraquara, SP, Brazil
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.description.sponsorshipCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
dc.format.extent83-86
dc.identifierhttp://dx.doi.org/10.1016/j.inoche.2010.09.037
dc.identifier.citationInorganic Chemistry Communications. Amsterdam: Elsevier B.V., v. 14, n. 1, p. 83-86, 2011.
dc.identifier.doi10.1016/j.inoche.2010.09.037
dc.identifier.issn1387-7003
dc.identifier.lattes3300223970814448
dc.identifier.lattes7927677053650819
dc.identifier.orcid0000-0002-0057-7964
dc.identifier.urihttp://hdl.handle.net/11449/26021
dc.identifier.wosWOS:000287269000021
dc.language.isoeng
dc.publisherElsevier B.V.
dc.relation.ispartofInorganic Chemistry Communications
dc.relation.ispartofjcr1.810
dc.relation.ispartofsjr0,430
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.subjectSupramolecular chemistryen
dc.subjectC-H center dot center dot center dot pi interactionsen
dc.subjectCyclopalladateden
dc.subjectMetalloaromaticityen
dc.titleSelf-assembly of cyclometallated Pd(II) compounds directed by C-H center dot center dot center dot pi interactions: A structural evidence for metalloaromaticity in a cyclopalladated ringen
dc.typeArtigo
dcterms.licensehttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dcterms.rightsHolderElsevier B.V.
dspace.entity.typePublication
unesp.author.lattes3300223970814448[5]
unesp.author.lattes7927677053650819[6]
unesp.author.orcid0000-0002-0057-7964[6]
unesp.campusUniversidade Estadual Paulista (UNESP), Instituto de Química, Araraquarapt
unesp.departmentQuímica Inorgânica - IQARpt

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Araraquara - IQAR - Instituto de Química