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Crystallization and optical properties of CCTO thin films under pressure influence

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CCTO thin films were deposited on Pt(111)/Ti/SiO 2/Si substrates using a chemical (polymeric precursor) and pressure method. The pressure effects on the CCTO thin films were evaluated by XRD, FEG-SEM and optical properties. Pressure films were found to be more homogeneous and dense than chemical deposition films. Pressure also leaded to an increase in the photoluminescence emission; it is suggested that the displacement of Ti in the titanate clusters, favors the charge transference from TiO 6 to [TiO 5V o z], TiO 5V o z] to [CaO 11V o z] and [TiO 5V o z] to [CuO 4] x. The low synthesis temperature used in the pressure method allows the deposition of films on less expensive substrates (i.e. glass, aluminum, polymer and others).

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CCTO, Pressure method, Thin films, Chemical deposition, Deposition of films, FEG-SEM, Photoluminescence emission, Polymeric precursors, Pressure films, Pt(111), Synthesis temperatures, TiO, XRD, Aluminum coatings, Exhibitions, Nanotechnology, Optical properties, Platinum, Polymer films, Polymers, Pressure effects, Vapor deposition, Nanocomposite films

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Inglês

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Technical Proceedings of the 2012 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2012, p. 698-701.

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