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Structure of copper(II) complexes adsorbed on functionalized polyhedral oligomeric silsesquioxane

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dc.contributor.authorDias Filho, Newton Luiz [UNESP]
dc.contributor.authorCosta, Reginaldo Mendonca [UNESP]
dc.contributor.authorSchultz, Mario Sergio
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniversidade de São Paulo (USP)
dc.date.accessioned2014-05-20T13:29:45Z
dc.date.available2014-05-20T13:29:45Z
dc.date.issued2008-06-02
dc.description.abstractThe 3-amino-1,2,4-triazole-modified silsesquioxane nanoplatforms have been prepared and characterized. The silsesquioxane nanocages readily react with CuX(2) in aqueous solution to form copper complex-substituted silsesquioxanes. Adsorption isotherms of CuX(2) from aqueous solution were studied at 25 degrees C. The electronic and ESR spectral parameters indicated that the copper ion is in a distorted-tetragonal symmetry field. (C) 2007 Elsevier B.V. All rights reserved.en
dc.description.affiliationUniv Estadual Paulista, Dept Quim & Fis, BR-15385000 Ilha Solteira, SP, Brazil
dc.description.affiliationUSP, Inst Quim São Carlos, BR-13566 São Carlos, SP, Brazil
dc.description.affiliationUnespUniv Estadual Paulista, Dept Quim & Fis, BR-15385000 Ilha Solteira, SP, Brazil
dc.format.extent2314-2320
dc.identifierhttp://dx.doi.org/10.1016/j.ica.2007.11.004
dc.identifier.citationInorganica Chimica Acta. Lausanne: Elsevier B.V. Sa, v. 361, n. 8, p. 2314-2320, 2008.
dc.identifier.doi10.1016/j.ica.2007.11.004
dc.identifier.issn0020-1693
dc.identifier.lattes1509480515046572
dc.identifier.urihttp://hdl.handle.net/11449/10063
dc.identifier.wosWOS:000256093600016
dc.language.isoeng
dc.publisherElsevier B.V. Sa
dc.relation.ispartofInorganica Chimica Acta
dc.relation.ispartofjcr2.264
dc.relation.ispartofsjr0,485
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.subjectcopper complexen
dc.subjectsilsesquioxaneen
dc.subjectfuctionalized silsesquioxaneen
dc.subjectadsorption isothermsen
dc.titleStructure of copper(II) complexes adsorbed on functionalized polyhedral oligomeric silsesquioxaneen
dc.typeArtigo
dcterms.licensehttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dcterms.rightsHolderElsevier B.V. Sa
dspace.entity.typePublication
unesp.author.lattes1509480515046572
unesp.campusUniversidade Estadual Paulista (UNESP), Faculdade de Engenharia, Ilha Solteirapt
unesp.departmentFísica e Química - FEISpt

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Ilha Solteira - FEIS - Faculdade de Engenharia