Publicação: Comportamento térmico de compostos ciclopaladados binucleares contendo azo-ligantes aniônicos
| dc.contributor.author | De Almeida, Eduardo Tonon [UNESP] | |
| dc.contributor.author | Mauro, Antonio Eduardo [UNESP] | |
| dc.contributor.author | Santana, Anderson Martinez [UNESP] | |
| dc.contributor.institution | Universidade Estadual Paulista (UNESP) | |
| dc.contributor.institution | UCB | |
| dc.date.accessioned | 2022-04-28T20:00:44Z | |
| dc.date.available | 2022-04-28T20:00:44Z | |
| dc.date.issued | 2002-12-01 | |
| dc.description.abstract | This paper deals with the thermal behavior study of cyclopalladated complexes obtained from reactions of [Pd(dmba)N3l2 (1), dmba = N,N-dimethylbenzylamine, with azole-compunds, such as, the anionic ligands pyrazolate (pz), imidazolate (imz) and 3.5-dimethyl-pyrazolate (3.5-dmpz). The characterization of the binuclear complexes [Pd(dmba)(μ-pz)]2 (2), [Pd(dmba)(μ-imz)]2 (3) and [Pd(dmba)(μ-3.5-dmpz)]2 (4) was carried out by elemental analysis, IR and NMR spectroscope Their thermal behaviour has been investigated and the final product was identified by X-ray powder diffractometry which showed the formation of Pd(0) as final decomposition product. | en |
| dc.description.affiliation | Depto. de Quimica Geral e Inorganica Instituto de Química UNESP, 14801-970 Araraquara, SP | |
| dc.description.affiliation | Curso de Química UCB, 72030-170 Taguatinga, Brasilia, DF | |
| dc.description.affiliationUnesp | Depto. de Quimica Geral e Inorganica Instituto de Química UNESP, 14801-970 Araraquara, SP | |
| dc.format.extent | 201-210 | |
| dc.identifier.citation | Ecletica Quimica, v. 27, p. 201-210. | |
| dc.identifier.issn | 0100-4670 | |
| dc.identifier.scopus | 2-s2.0-18844476840 | |
| dc.identifier.uri | http://hdl.handle.net/11449/224548 | |
| dc.language.iso | por | |
| dc.relation.ispartof | Ecletica Quimica | |
| dc.source | Scopus | |
| dc.subject | 3,5-dimethyl-pyrazolate | |
| dc.subject | Cyclopalladated | |
| dc.subject | Imidazolate | |
| dc.subject | Pyrazolate | |
| dc.subject | Thermal analysis | |
| dc.title | Comportamento térmico de compostos ciclopaladados binucleares contendo azo-ligantes aniônicos | pt |
| dc.title.alternative | Thermal behaviour of binuclear cyclopalladated compounds containing anionic azo-ligands | en |
| dc.type | Artigo | |
| dspace.entity.type | Publication | |
| unesp.campus | Universidade Estadual Paulista (UNESP), Instituto de Química, Araraquara | pt |
| unesp.department | Química Inorgânica - IQAR | pt |