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Preparation and properties of ferroelectric BaTiO3 thin films produced by the polymeric precursor method

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Ferroelectric barium titanate thin films were produced by the polymeric precursor method. In this technique, the desired metal cations are chelated in a solution using a hydroxycarboxylic acid as the chelating agent. Barium carbonate and titanium IV isopropoxide were used as precursors for the citrate solution. Ethylene glycol and citric acid were used as polymerization/complexation agents for the process. The crystalline structure of the film annealed at 700 °C had a single perovskite phase with a tetragonal structure. The BaTiO3 film showed good P-E hysteresis loops and C-V characteristics due to the switched ferroelectric domains.

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Atomic force microscopy, Barium titanate, Complexation, Ferroelectricity, Glycols, Hysteresis, Perovskite, Polymerization, Scanning electron microscopy, Thin films, X ray diffraction, Metal-ferroelectric-metal capacitors, Polymeric precursor method, Ferroelectric materials

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Inglês

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Journal of Materials Science Letters, v. 19, n. 16, p. 1457-1459, 2000.

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