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Turbinatine, a potential key intermediate in the biosynthesis of corynanthean-type indole alkaloids

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dc.contributor.authorCardoso, C. L.
dc.contributor.authorSilva, DHS
dc.contributor.authorTomazela, D. M.
dc.contributor.authorVerli, H.
dc.contributor.authorYoung, MCM
dc.contributor.authorFurlan, Maysa [UNESP]
dc.contributor.authorEberlin, M. N.
dc.contributor.authorBolzani, Vanderlan da Silva [UNESP]
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniversidade Estadual de Campinas (UNICAMP)
dc.contributor.institutionInst Bot
dc.contributor.institutionUniversidade Federal do Rio Grande do Sul (UFRGS)
dc.date.accessioned2014-05-20T15:22:43Z
dc.date.available2014-05-20T15:22:43Z
dc.date.issued2003-07-01
dc.description.abstractExtraction of the leaves of Chimarrhis turbinata has led to the isolation of turbinatine (1), a new corynanthean-type indole alkaloid, besides four known indole alkaloids, strictosidine, 5alpha-carboxystrictosidine, vallesiachotamine, and isovallesiachotamine. The structural determination of 1 was based on 1D and 2D spectroscopic data. An evaluation of the DNA-damaging activities of the isolates was performed by means of a bioassay using mutant strains of Saccharomyces cerevisiae, which indicated these compounds were weakly active.en
dc.description.affiliationUniv Estadual Paulista, UNESP, Inst Quim, BR-14801970 São Paulo, Brazil
dc.description.affiliationUniv Estadual Campinas, UNICAMP, Inst Quim, Thompson Mass Spect Lab, BR-13083970 Campinas, SP, Brazil
dc.description.affiliationInst Bot, Secao Fisiol & Bioquim Plantas, BR-10051 São Paulo, SP, Brazil
dc.description.affiliationUniv Fed Rio Grande Sul, Ctr Biotecnol, UFRGS, BR-91501970 Porto Alegre, RS, Brazil
dc.description.affiliationUnespUniv Estadual Paulista, UNESP, Inst Quim, BR-14801970 São Paulo, Brazil
dc.format.extent1017-1021
dc.identifierhttp://dx.doi.org/10.1021/np020547m
dc.identifier.citationJournal of Natural Products. Washington: Amer Chemical Soc, v. 66, n. 7, p. 1017-1021, 2003.
dc.identifier.doi10.1021/np020547m
dc.identifier.issn0163-3864
dc.identifier.lattes4702004904231248
dc.identifier.lattes1308042794786872
dc.identifier.lattes4484083685251673
dc.identifier.urihttp://hdl.handle.net/11449/33652
dc.identifier.wosWOS:000184412800026
dc.language.isoeng
dc.publisherAmer Chemical Soc
dc.relation.ispartofJournal of Natural Products
dc.relation.ispartofjcr3.885
dc.relation.ispartofsjr1,368
dc.rights.accessRightsAcesso restritopt
dc.sourceWeb of Science
dc.titleTurbinatine, a potential key intermediate in the biosynthesis of corynanthean-type indole alkaloidsen
dc.typeEditorialpt
dcterms.licensehttp://pubs.acs.org/paragonplus/copyright/jpa_form_a.pdf
dcterms.rightsHolderAmer Chemical Soc
dspace.entity.typePublication
relation.isOrgUnitOfPublicationbc74a1ce-4c4c-4dad-8378-83962d76c4fd
relation.isOrgUnitOfPublication.latestForDiscoverybc74a1ce-4c4c-4dad-8378-83962d76c4fd
unesp.author.lattes4702004904231248
unesp.author.lattes1308042794786872
unesp.author.lattes4484083685251673
unesp.campusUniversidade Estadual Paulista (UNESP), Instituto de Química, Araraquarapt
unesp.departmentQuímica Orgânica - IQARpt

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Araraquara - IQAR - Instituto de Química