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A Tetranuclear Silver-Thiourea Cluster

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dc.contributor.authorFernandes, José A. [UNESP]
dc.contributor.authorSegura, Daniel F.
dc.contributor.authorNetto, Adelino V. G.
dc.contributor.authorFrem, Regina C. G.
dc.contributor.authorMauro, Antonio E. [UNESP]
dc.contributor.authorPaz, Filipe A. Almeida [UNESP]
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2018-12-11T16:58:40Z
dc.date.available2018-12-11T16:58:40Z
dc.date.issued2015-09-30
dc.description.abstractDuring the synthesis of the bioactive complex [Ag(phen)(μ-tu)]<inf>2</inf>(NO<inf>3</inf>)<inf>2</inf> (1), some crystals of a new compound were isolated. This crystalline compound, [Ag<inf>4</inf>(μ-tu)<inf>5</inf>(tu)<inf>6</inf>](NO<inf>3</inf>)<inf>4</inf>·7Phen (2) (tu = thiourea, Phen = 1,10-phenanthroline), is a novelty for at least two reasons: (i) it is the first tetranuclear silver and thiourea cluster; (ii) it is the first crystal structure with seven neutral, and uncoordinated, phen molecules. Phen molecules pack forming an infinite column, and the tu ligands form an intricate network of hydrogen bonds with the Phen and nitrate entities.en
dc.description.affiliationDepartamento de Química Geral e Inorgânica, Instituto de Química, UNESP-Univ Estadual Paulista
dc.description.affiliationDepartment of Chemistry, CICECO, University of Aveiro
dc.description.affiliationUnespDepartamento de Química Geral e Inorgânica, Instituto de Química, UNESP-Univ Estadual Paulista
dc.format.extent410-418
dc.identifierhttp://dx.doi.org/10.1007/s10870-015-0608-9
dc.identifier.citationJournal of Chemical Crystallography, v. 45, n. 8-9, p. 410-418, 2015.
dc.identifier.doi10.1007/s10870-015-0608-9
dc.identifier.file2-s2.0-84942590451.pdf
dc.identifier.issn1074-1542
dc.identifier.lattes7927677053650819
dc.identifier.lattes8534138813417161
dc.identifier.orcid0000-0002-0057-7964
dc.identifier.orcid0000-0003-1574-681X
dc.identifier.scopus2-s2.0-84942590451
dc.identifier.urihttp://hdl.handle.net/11449/172103
dc.language.isoeng
dc.relation.ispartofJournal of Chemical Crystallography
dc.relation.ispartofsjr0,209
dc.rights.accessRightsAcesso abertopt
dc.sourceScopus
dc.subjectSilver and thiourea cluster
dc.subjectSupramolecular interactions
dc.titleA Tetranuclear Silver-Thiourea Clusteren
dc.typeArtigopt
dspace.entity.typePublication
relation.isOrgUnitOfPublicationbc74a1ce-4c4c-4dad-8378-83962d76c4fd
relation.isOrgUnitOfPublication.latestForDiscoverybc74a1ce-4c4c-4dad-8378-83962d76c4fd
unesp.author.lattes7927677053650819[3]
unesp.author.lattes3300223970814448[5]
unesp.author.lattes8534138813417161[4]
unesp.author.orcid0000-0002-0057-7964[3]
unesp.author.orcid0000-0003-1574-681X[4]
unesp.campusUniversidade Estadual Paulista (UNESP), Instituto de Química, Araraquarapt
unesp.departmentQuímica Inorgânica - IQARpt

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