Synthesis and characterization of a new platinum(II) complex with L-mimosine
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Coadvisor
Graduate program
Undergraduate course
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Publisher
Taylor & Francis Ltd
Type
Article
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Acesso restrito
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Abstract
Synthesis and characterization of a new Pt(II)-mimosine complex are described. Elemental, mass spectrometry and thermal analyses for the complex are consistent with the formula [PtCl2(C8H10N2O4)]center dot 1.5H(2)O. C-13 NMR, N-15 NMR and infrared spectroscopy indicate coordination of the ligand to Pt(II) through the N and O atoms in a square-planar geometry. The final residue after thermal treatment was identified as metallic Pt. The complex is soluble in dimethylsulfoxide.
Description
Keywords
platinum(II), L-mimosine, amino acids, metal complex, N-15 NMR
Language
English
Citation
Journal of Coordination Chemistry. Abingdon: Taylor & Francis Ltd, v. 58, n. 16, p. 1477-1483, 2005.
