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Dehydration of d-fructose to 5-hydroxymethyl-2-furfural in DMSO using a hydrophilic sulfonated silica catalyst in a process promoted by microwave irradiation

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dc.contributor.authorBarbosa, Sandro L.
dc.contributor.authorde S. Freitas, Milton
dc.contributor.authordos Santos, Wallans T. P.
dc.contributor.authorNelson, David Lee
dc.contributor.authorKlein, Stanlei I. [UNESP]
dc.contributor.authorClososki, Giuliano Cesar
dc.contributor.authorCaires, Franco J.
dc.contributor.authorBaroni, Adriano C. M.
dc.contributor.authorWentz, Alexandre P.
dc.contributor.institutionUniversidade Federal de Viçosa (UFV)
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniversidade de São Paulo (USP)
dc.contributor.institutionUniversidade Federal de Mato Grosso do Sul (UFMS)
dc.contributor.institutionCentro universitário SENAI-CIMATEC
dc.date.accessioned2021-06-25T10:50:04Z
dc.date.available2021-06-25T10:50:04Z
dc.date.issued2021-12-01
dc.description.abstractSiO2-SO3H, with a surface area of 115 m2/g, pore volumes of 0.38 cm3g−1 and 1.32 mmol H+/g, was used as a 10% w/w catalyst for the preparation of 5-hydroxymethyl-2-furfural (HMF) from fructose. A conversion of 100% was achieved in a microwave reactor during 10 min at 150 °C in DMSO, with 100% selectivity for HMF, at a molar ratio of fructose: DMSO equal to 1:56. The catalyst could be re-used three times.en
dc.description.affiliationDepartment of Pharmacy Universidade Federal dos Vales do Jequitinhonha e Mucuri-UFVJM, Campus JK, Rodovia MGT 367 - Km 583, nº 5.000, Alto da Jacuba
dc.description.affiliationDepartment of General and Inorganic Chemistry Institute of Chemistry São Paulo State University-Unesp, R. Prof. Francisco Degni 55, Quitandinha
dc.description.affiliationDepartment of Physics and Chemistry Faculdade de Ciências Farmacêuticas de Ribeirão Preto São Paulo University-USP, Av. do Café s/n
dc.description.affiliationFaculdade de Ciências Farmacêuticas Alimentos e Nutrição Universidade Federal do Mato Grosso do Sul - UFMS, Av. Costa e Silva, s.n.
dc.description.affiliationCentro universitário SENAI-CIMATEC, Av. Orlando Gomes, 1845, Piatã
dc.description.affiliationUnespDepartment of General and Inorganic Chemistry Institute of Chemistry São Paulo State University-Unesp, R. Prof. Francisco Degni 55, Quitandinha
dc.identifierhttp://dx.doi.org/10.1038/s41598-020-80285-2
dc.identifier.citationScientific Reports, v. 11, n. 1, 2021.
dc.identifier.dimensionspub.1134738464
dc.identifier.doi10.1038/s41598-020-80285-2
dc.identifier.issn2045-2322
dc.identifier.orcid0000-0002-5060-6479
dc.identifier.orcid0000-0001-7026-8502
dc.identifier.orcid0000-0001-7435-3675
dc.identifier.orcid0000-0001-7605-4150
dc.identifier.orcid0000-0002-0294-5345
dc.identifier.orcid0000-0002-4579-6837
dc.identifier.pmcidPMC7820282
dc.identifier.pmid33479324
dc.identifier.scopus2-s2.0-85099759990
dc.identifier.urihttp://hdl.handle.net/11449/207169
dc.language.isoeng
dc.publisherSpringer Nature
dc.relation.ispartofScientific Reports
dc.rights.accessRightsAcesso abertopt
dc.rights.sourceRightsoa_all
dc.rights.sourceRightsgold
dc.sourceScopus
dc.sourceDimensions
dc.titleDehydration of d-fructose to 5-hydroxymethyl-2-furfural in DMSO using a hydrophilic sulfonated silica catalyst in a process promoted by microwave irradiationen
dc.typeArtigopt
dspace.entity.typePublication
relation.isOrgUnitOfPublicationbc74a1ce-4c4c-4dad-8378-83962d76c4fd
relation.isOrgUnitOfPublication.latestForDiscoverybc74a1ce-4c4c-4dad-8378-83962d76c4fd
unesp.campusUniversidade Estadual Paulista (UNESP), Instituto de Química, Araraquarapt
unesp.departmentQuímica Inorgânica - IQARpt

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