Publicação: Dehydration of d-fructose to 5-hydroxymethyl-2-furfural in DMSO using a hydrophilic sulfonated silica catalyst in a process promoted by microwave irradiation
| dc.contributor.author | Barbosa, Sandro L. | |
| dc.contributor.author | de S. Freitas, Milton | |
| dc.contributor.author | dos Santos, Wallans T. P. | |
| dc.contributor.author | Nelson, David Lee | |
| dc.contributor.author | Klein, Stanlei I. [UNESP] | |
| dc.contributor.author | Clososki, Giuliano Cesar | |
| dc.contributor.author | Caires, Franco J. | |
| dc.contributor.author | Baroni, Adriano C. M. | |
| dc.contributor.author | Wentz, Alexandre P. | |
| dc.contributor.institution | Universidade Federal de Viçosa (UFV) | |
| dc.contributor.institution | Universidade Estadual Paulista (Unesp) | |
| dc.contributor.institution | Universidade de São Paulo (USP) | |
| dc.contributor.institution | Universidade Federal de Mato Grosso do Sul (UFMS) | |
| dc.contributor.institution | Centro universitário SENAI-CIMATEC | |
| dc.date.accessioned | 2021-06-25T10:50:04Z | |
| dc.date.available | 2021-06-25T10:50:04Z | |
| dc.date.issued | 2021-12-01 | |
| dc.description.abstract | SiO2-SO3H, with a surface area of 115 m2/g, pore volumes of 0.38 cm3g−1 and 1.32 mmol H+/g, was used as a 10% w/w catalyst for the preparation of 5-hydroxymethyl-2-furfural (HMF) from fructose. A conversion of 100% was achieved in a microwave reactor during 10 min at 150 °C in DMSO, with 100% selectivity for HMF, at a molar ratio of fructose: DMSO equal to 1:56. The catalyst could be re-used three times. | en |
| dc.description.affiliation | Department of Pharmacy Universidade Federal dos Vales do Jequitinhonha e Mucuri-UFVJM, Campus JK, Rodovia MGT 367 - Km 583, nº 5.000, Alto da Jacuba | |
| dc.description.affiliation | Department of General and Inorganic Chemistry Institute of Chemistry São Paulo State University-Unesp, R. Prof. Francisco Degni 55, Quitandinha | |
| dc.description.affiliation | Department of Physics and Chemistry Faculdade de Ciências Farmacêuticas de Ribeirão Preto São Paulo University-USP, Av. do Café s/n | |
| dc.description.affiliation | Faculdade de Ciências Farmacêuticas Alimentos e Nutrição Universidade Federal do Mato Grosso do Sul - UFMS, Av. Costa e Silva, s.n. | |
| dc.description.affiliation | Centro universitário SENAI-CIMATEC, Av. Orlando Gomes, 1845, Piatã | |
| dc.description.affiliationUnesp | Department of General and Inorganic Chemistry Institute of Chemistry São Paulo State University-Unesp, R. Prof. Francisco Degni 55, Quitandinha | |
| dc.identifier | http://dx.doi.org/10.1038/s41598-020-80285-2 | |
| dc.identifier.citation | Scientific Reports, v. 11, n. 1, 2021. | |
| dc.identifier.doi | 10.1038/s41598-020-80285-2 | |
| dc.identifier.issn | 2045-2322 | |
| dc.identifier.scopus | 2-s2.0-85099759990 | |
| dc.identifier.uri | http://hdl.handle.net/11449/207169 | |
| dc.language.iso | eng | |
| dc.relation.ispartof | Scientific Reports | |
| dc.source | Scopus | |
| dc.title | Dehydration of d-fructose to 5-hydroxymethyl-2-furfural in DMSO using a hydrophilic sulfonated silica catalyst in a process promoted by microwave irradiation | en |
| dc.type | Artigo | |
| dspace.entity.type | Publication | |
| unesp.campus | Universidade Estadual Paulista (UNESP), Instituto de Química, Araraquara | pt |
| unesp.department | Química Inorgânica - IQAR | pt |