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Dba-free palladium intermediates of the Heck-Matsuda reaction

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dc.contributor.authorMacHado, Angelo H. L.
dc.contributor.authorMilagre, Humberto M. S. [UNESP]
dc.contributor.authorEberlin, Livia S.
dc.contributor.authorSabino, Adão A.
dc.contributor.authorCorreia, Carlos Roque D.
dc.contributor.authorEberlin, Marcos N.
dc.contributor.institutionUniversidade Estadual de Campinas (UNICAMP)
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniversidade Federal de Minas Gerais (UFMG)
dc.date.accessioned2014-05-27T11:29:32Z
dc.date.available2014-05-27T11:29:32Z
dc.date.issued2013-05-28
dc.description.abstractThe dba-free Heck-Matsuda reaction was investigated via direct ESI-MS(/MS) monitoring. Palladium species involved in the reduction of Pd(ii) during a Wacker type reaction and several dba-free arylpalladium transient complexes were detected and characterized. Based on these findings, a more comprehensible catalytic cycle for this pivotal reaction is suggested. © 2013 The Royal Society of Chemistry.en
dc.description.affiliationChemistry Institute University of Campinas - UNICAMP, Campinas
dc.description.affiliationThomson Laboratory University of Campinas - UNICAMP, Campinas
dc.description.affiliationInstitute of Biosciences Universidade Estadual Paulista - UNESP, Rio-Claro
dc.description.affiliationDepartment of Chemistry Federal University of Minas Gerais - UFMG, Belo Horizonte
dc.description.affiliationUnespInstitute of Biosciences Universidade Estadual Paulista - UNESP, Rio-Claro
dc.format.extent3277-3281
dc.identifierhttp://dx.doi.org/10.1039/c3ob40142a
dc.identifier.citationOrganic and Biomolecular Chemistry, v. 11, n. 20, p. 3277-3281, 2013.
dc.identifier.doi10.1039/c3ob40142a
dc.identifier.issn1477-0520
dc.identifier.scopus2-s2.0-84877257398
dc.identifier.urihttp://hdl.handle.net/11449/75444
dc.identifier.wosWOS:000318306400002
dc.language.isoeng
dc.relation.ispartofOrganic and Biomolecular Chemistry
dc.relation.ispartofjcr3.423
dc.relation.ispartofsjr1,281
dc.rights.accessRightsAcesso restritopt
dc.sourceScopus
dc.subjectCatalytic cycles
dc.subjectHeck-matsuda reactions
dc.subjectPalladium intermediates
dc.subjectPalladium species
dc.subjectTransient complexes
dc.subjectWacker-type reactions
dc.subjectChemistry
dc.subjectPositive ions
dc.subjectReaction intermediates
dc.titleDba-free palladium intermediates of the Heck-Matsuda reactionen
dc.typeArtigopt
dcterms.licensehttp://www.rsc.org/AboutUs/Copyright/Authordeposition.asp
dspace.entity.typePublication
unesp.author.orcid0000-0001-5564-6675[5]
unesp.author.orcid0000-0001-9468-1166[2]
unesp.campusUniversidade Estadual Paulista (UNESP), Instituto de Biociências, Rio Claropt

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Rio Claro - IB - Instituto de Biociências