Publicação: Palladium orthometallated complexes containing acetophenoneoxime: Synthesis, crystal structures and hirshfeld surface analysis
dc.contributor.author | Bozza, Gabriela F. [UNESP] | |
dc.contributor.author | de Farias, Renan L. [UNESP] | |
dc.contributor.author | de Souza, Ronan F.F. [UNESP] | |
dc.contributor.author | Rocha, Fillipe V. | |
dc.contributor.author | Barra, Carolina V. | |
dc.contributor.author | Deflon, Victor M. | |
dc.contributor.author | de Almeida, Eduardo T. | |
dc.contributor.author | Mauro, Antonio E. [UNESP] | |
dc.contributor.author | Netto, Adelino V.G. [UNESP] | |
dc.contributor.institution | Universidade Estadual Paulista (Unesp) | |
dc.contributor.institution | Universidade Federal de São Carlos (UFSCar) | |
dc.contributor.institution | Ciência e Tecnologia de São Paulo | |
dc.contributor.institution | Universidade de São Paulo (USP) | |
dc.contributor.institution | Instituto de Química | |
dc.date.accessioned | 2019-10-06T16:48:01Z | |
dc.date.available | 2019-10-06T16:48:01Z | |
dc.date.issued | 2019-01-05 | |
dc.description.abstract | The bridge-splitting reaction between [Pd(C2,N-aphox)(μ-Cl)]2 and phosphines (L), in a 1:2 ratio, yielded neutral mononuclear cyclopalladated compounds of the type [PdCl(C2,N-aphox)(L)] {aphox = acetophenoneoxime; L = triphenylphosphine (1), tris(4-fluorophenyl)phosphine (2), tri-cyclohexylphosphine (3), diphenyl(p-toluyl)phosphine (4), tris-(4-methoxyphenyl)phosphine (5) and tri(p-toluyl)phosphine (6)}. The compounds were characterized by elemental analyses, IR and 1H-, 13C{1H}- and 31P{1H}-NMR spectroscopies. The crystal and molecular structures of 1–5 were determined by single-crystal X-ray diffraction. After that, the Hirshfeld surface calculations were carried out to explore the nature and major contributions of different intermolecular contacts towards crystal packing stability. | en |
dc.description.affiliation | UNESP - Univ Estadual Paulista Institute of Chemistry | |
dc.description.affiliation | UFSCar Univ Federal de São Carlos Departamento de Química | |
dc.description.affiliation | Instituto Federal de Educação Ciência e Tecnologia de São Paulo, Campus Araraquara | |
dc.description.affiliation | Instituto de Química de São Carlos Universidade de São Paulo | |
dc.description.affiliation | UNIFAL - MG - Univ Federal de Alfenas Instituto de Química | |
dc.description.affiliationUnesp | UNESP - Univ Estadual Paulista Institute of Chemistry | |
dc.description.sponsorship | Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) | |
dc.description.sponsorship | Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) | |
dc.description.sponsorship | Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) | |
dc.description.sponsorshipId | FAPESP: 2012/15486-3 | |
dc.description.sponsorshipId | FAPESP: 2014/11340-0 | |
dc.description.sponsorshipId | FAPESP: 2016/17711-5 | |
dc.description.sponsorshipId | CNPq: 422105/2016-3 | |
dc.format.extent | 195-207 | |
dc.identifier | http://dx.doi.org/10.1016/j.molstruc.2018.07.108 | |
dc.identifier.citation | Journal of Molecular Structure, v. 1175, p. 195-207. | |
dc.identifier.doi | 10.1016/j.molstruc.2018.07.108 | |
dc.identifier.issn | 0022-2860 | |
dc.identifier.scopus | 2-s2.0-85053035947 | |
dc.identifier.uri | http://hdl.handle.net/11449/189662 | |
dc.language.iso | eng | |
dc.relation.ispartof | Journal of Molecular Structure | |
dc.rights.accessRights | Acesso aberto | |
dc.source | Scopus | |
dc.subject | Crystal structure | |
dc.subject | Cyclopalladated compounds | |
dc.subject | Hirshfeld surface analysis | |
dc.subject | Oximes | |
dc.title | Palladium orthometallated complexes containing acetophenoneoxime: Synthesis, crystal structures and hirshfeld surface analysis | en |
dc.type | Artigo | |
dspace.entity.type | Publication | |
unesp.author.lattes | 3300223970814448[8] | |
unesp.author.orcid | 0000-0002-0057-7964[9] | |
unesp.campus | Universidade Estadual Paulista (UNESP), Instituto de Química, Araraquara | pt |
unesp.department | Bioquímica e Tecnologia - IQ | pt |