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fac-[RuCl3(no)(dppb)] (I) and mer-[RuCl3(NO)(diop)] (II) complexes: Syntheses, characterization and x-ray structures

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dc.contributor.authorVon Poelhsitz, Gustavo [UNESP]
dc.contributor.authorDe Araujo, Màrcio Perez [UNESP]
dc.contributor.authorDe Oliveira, Luiz Antonio Andrade [UNESP]
dc.contributor.authorQueiroz, Salete Linhares
dc.contributor.authorEllena, Javier
dc.contributor.authorCastellano, Eduardo Ernesto
dc.contributor.authorFerreira, Antonio Gilberto
dc.contributor.authorBatista, Alzir Azovedo [UNESP]
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionFaculdade de Ciências de Barretos
dc.contributor.institutionUniversidade de São Paulo (USP)
dc.contributor.institutionUniversidade Federal de São Carlos (UFSCar)
dc.date.accessioned2014-05-27T11:20:30Z
dc.date.available2014-05-27T11:20:30Z
dc.date.issued2002-10-01
dc.description.abstractThe fac-[RuCl3(NO)(dppb)] complex I has been prepared from solution of the correspondent mer isomer in refluxing methanol (dppb = 1,4-bis(diphenylphosphino)butane). The mer-[RuCl3(NO)(diop)] (II) has been obtained from the mer-[RuCl3(diop)(H2O)] by bubbling NO for 1 h in dichloromethane (diop = 2S,3S-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane). The complexes have been characterized by microanalysis, cyclic voltammetry (CV), IR and 31P{1H} NMR spectroscopies. The crystal and molecular structures of these two compounds have been determined from X-ray studies. The mer-[RuCl3(NO)(dppb)] isomer III was characterized in solution by NMR spectra (31P{1H}, 1H{31P}, 31P-1H HETCORR, COSY 1H-1H, HMQC 1H-13C and HMBC 1H-13C). © 2002 Elsevier Science Ltd. All rights reserved.en
dc.description.affiliationInstituto de Química Universidade Estadual Paulista, C.P. 355, CEP 14800-900 Araraquara, SP
dc.description.affiliationFaculdade de Ciências de Barretos, Av. Prof. Roberto Frade Monte, 389, CEP 14783-226 Barretos, SP
dc.description.affiliationInstituto de Física de São Carlos Universidade de São Paulo, C.P. 369, CEP 13560-970 São Carlos, SP
dc.description.affiliationDepartamento de Química Universidade Federal de São Carlos, C.P. 676, CEP 13565-905 São Carlos, SP
dc.description.affiliationUnespInstituto de Química Universidade Estadual Paulista, C.P. 355, CEP 14800-900 Araraquara, SP
dc.format.extent2221-2225
dc.identifierhttp://dx.doi.org/10.1016/S0277-5387(02)01166-X
dc.identifier.citationPolyhedron, v. 21, n. 22, p. 2221-2225, 2002.
dc.identifier.doi10.1016/S0277-5387(02)01166-X
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-0036792080
dc.identifier.urihttp://hdl.handle.net/11449/66978
dc.identifier.wosWOS:000178534400003
dc.language.isoeng
dc.relation.ispartofPolyhedron
dc.relation.ispartofjcr2.067
dc.relation.ispartofsjr0,472
dc.rights.accessRightsAcesso restritopt
dc.sourceScopus
dc.subjectDiop
dc.subjectDppb
dc.subjectNitrosyl complexes
dc.subjectNMR spectra
dc.subjectRuthenium(II)
dc.subjectX-ray structures
dc.subjectisopropylidene 2,3 dihydroxy 1,4 bis(diphenylphosphino)butane
dc.subjectmetal complex
dc.subjectmethanol 1,4 bis(diphenylphosphino)butane
dc.subjectruthenium complex
dc.subjectunclassified drug
dc.subjectanalytic method
dc.subjectcatalysis
dc.subjectchemical analysis
dc.subjectcomplex formation
dc.subjectnuclear magnetic resonance
dc.subjectphase transition
dc.subjectstructure analysis
dc.subjectsynthesis
dc.subjectX ray analysis
dc.titlefac-[RuCl3(no)(dppb)] (I) and mer-[RuCl3(NO)(diop)] (II) complexes: Syntheses, characterization and x-ray structuresen
dc.typeArtigopt
dcterms.licensehttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dspace.entity.typePublication
unesp.campusUniversidade Estadual Paulista (UNESP), Instituto de Química, Araraquarapt

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Araraquara - IQAR - Instituto de Química