Publicação: Synthesis, spectral and thermal studies on dicarboxylate-bridged palladium(II) coordination polymers. Part II
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Springer
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Artigo
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Resumo
The synthesis and thermal behavior of the new [Pd(fum)(bipy)] (n) center dot 2nH(2)O (1), [Pd(fum)(bpe)] (n) center dot nH(2)O (2) and [Pd(fum)(pz)] (n) center dot 3nH(2)O (3) {bipy = 4,4'-bipyridine, bpe = 1,2-bis(4-pyridyl)ethene and pz = pyrazine} fumarate complexes are described in this work as well their characterization by IR and (13)C CPMAS NMR spectroscopies. TG curves showed that the compounds released organic ligands and lattice water molecules in the temperature range of 46-491 A degrees C. In all the cases, metallic palladium was identified as the final residue.
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Palavras-chave
Palladium(II), Fumarate, N-based linear spacers, Thermal studies, Coordination polymers
Idioma
Inglês
Como citar
Journal of Thermal Analysis and Calorimetry. Dordrecht: Springer, v. 97, n. 1, p. 153-156, 2009.
