Publicação: Cyclometallated compounds of intramolecular coordination.
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Soc Brasileira Quimica
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This article supplies a review on the chemistry of cyclometallated compounds. Emphasis is given to those formed by cyclometallation reactions. In this class of complexes, called organometallic intramolecular-coordination compounds, a special attention is given to the reactivity of cyclometallated of palladium(II) due to their use in important chemical processes. Metal-carbon bonds in these palladium(II) complexes can undergo a large variety of insertion reactions and they offer a potentially important sequence in organic synthetic methodology,homogeneous catalysis and liquid crystals manufacturing.
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cyclometallated compounds, cyclometallation reaction, palladium (II) complexes
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Português
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Quimica Nova. São Paulo: Soc Brasileira Quimica, v. 19, n. 1, p. 59-72, 1996.
