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Operando XAS/Raman/MS monitoring of ethanol steam reforming reaction-regeneration cycles

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dc.contributor.authorPassos, Aline Ribeiro [UNESP]
dc.contributor.authorLa Fontaine, Camille
dc.contributor.authorMartins, Leandro [UNESP]
dc.contributor.authorPulcinelli, Sandra Helena [UNESP]
dc.contributor.authorSantilli, Celso Valentim [UNESP]
dc.contributor.authorBriois, Valérie
dc.contributor.institutionL'Orme des Merisiers BP48
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2019-10-06T16:57:54Z
dc.date.available2019-10-06T16:57:54Z
dc.date.issued2018-01-01
dc.description.abstractThe recyclability of a coked ethanol steam reforming catalyst (Co/Al2O3) is studied over several cycles. Oxidative regeneration burns coke, however some of the cobalt is oxidized. H2 produced during reforming promotes self-reactivation, restoring catalyst activity. The regeneration leads to the redispersion of smaller cobalt particles as a result of the Kirkendall effect.en
dc.description.affiliationSynchrotron SOLEIL L'Orme des Merisiers BP48
dc.description.affiliationUNESP-São Paulo State University Institute of Chemistry, Rua Professor Francisco Degni, 55
dc.description.affiliationUnespUNESP-São Paulo State University Institute of Chemistry, Rua Professor Francisco Degni, 55
dc.format.extent6297-6301
dc.identifierhttp://dx.doi.org/10.1039/c8cy01596a
dc.identifier.citationCatalysis Science and Technology, v. 8, n. 24, p. 6297-6301, 2018.
dc.identifier.doi10.1039/c8cy01596a
dc.identifier.issn2044-4761
dc.identifier.issn2044-4753
dc.identifier.lattes5584298681870865
dc.identifier.orcid0000-0002-8356-8093
dc.identifier.scopus2-s2.0-85058495234
dc.identifier.urihttp://hdl.handle.net/11449/189965
dc.language.isoeng
dc.relation.ispartofCatalysis Science and Technology
dc.rights.accessRightsAcesso restrito
dc.sourceScopus
dc.titleOperando XAS/Raman/MS monitoring of ethanol steam reforming reaction-regeneration cyclesen
dc.typeArtigo
dspace.entity.typePublication
unesp.author.lattes5584298681870865[5]
unesp.author.orcid0000-0002-8356-8093[5]
unesp.campusUniversidade Estadual Paulista (UNESP), Instituto de Química, Araraquarapt
unesp.departmentFísico-Química - IQARpt

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Araraquara - IQAR - Instituto de Química