Vibrational spectroscopy as a direct stereochemical probe for polyhydroxylated molecules
Carregando...
Fontes externas
Fontes externas
Data
Orientador
Coorientador
Pós-graduação
Curso de graduação
Título da Revista
ISSN da Revista
Título de Volume
Editor
Royal Soc Chemistry
Royal Society of Chemistry (RSC)
Royal Society of Chemistry (RSC)
Tipo
Artigo
Direito de acesso
Acesso restrito
Fontes externas
Fontes externas
Resumo
A simple IR and VCD spectra-structure relationship is proposed for the determination of the relative and absolute configurations of polyhydroxylated molecules using a series of styryl-pyrones as model compounds. Spectral signatures identified for free molecules and acetonide derivatives may be used for stereochemical assignments of related molecules without the aid of quantum-chemical calculations.
Descrição
Palavras-chave
Idioma
Inglês
Citação
Physical Chemistry Chemical Physics. Cambridge: Royal Soc Chemistry, v. 18, n. 45, p. 30903-30906, 2016.
