Shvo's catalyst in chemoenzymatic dynamic kinetic resolution of amines-inner or outer sphere mechanism?

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dc.contributor.authorVaz, Boniek G.
dc.contributor.authorMilagre, Cintia Duarte de Freitas [UNESP]
dc.contributor.authorEberlin, Marcos N.
dc.contributor.authorMilagre, Humberto Márcio Santos [UNESP]
dc.contributor.institutionUniversidade Federal de Goiás (UFG)
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniversidade Estadual de Campinas (UNICAMP)
dc.date.accessioned2014-05-27T11:30:52Z
dc.date.available2014-05-27T11:30:52Z
dc.date.issued2013-10-21
dc.description.abstractEvidence is provided for the inner-sphere mechanism with actual metal coordination of the racemic amine in the crucial hydrogen transfer step promoted by Shvo's catalyst of the chemoenzymatic dynamic kinetic resolution (DKR) of amines. Key intermediates involved in this H-transfer step were intercepted and continuously monitored by electrospray ionization mass spectrometry (ESI-MS) and characterized by their dissociation chemistries via ESI-MS/MS. © 2013 The Royal Society of Chemistry.en
dc.description.affiliationInstitute of Chemistry Federal University of Goiás Campus Samambaia, Caixa Postal 131, Goiânia Goiás CEP 74001-970
dc.description.affiliationDepartment of Organic Chemistry Institute of Chemistry Univ. Estadual Paulista UNESP, 14800-060 Araraquara SP
dc.description.affiliationThoMSon Mass Spectrometry Laboratory Institute of Chemistry University of Campinas UNICAMP, 13084-971 Campinas SP
dc.description.affiliationUnespDepartment of Organic Chemistry Institute of Chemistry Univ. Estadual Paulista UNESP, 14800-060 Araraquara SP
dc.format.extent6695-6698
dc.identifierhttp://dx.doi.org/10.1039/c3ob41318g
dc.identifier.citationOrganic and Biomolecular Chemistry, v. 11, n. 39, p. 6695-6698, 2013.
dc.identifier.doi10.1039/c3ob41318g
dc.identifier.issn1477-0520
dc.identifier.lattes1425748916849376
dc.identifier.orcid0000-0001-5627-8616
dc.identifier.scopus2-s2.0-84884472099
dc.identifier.urihttp://hdl.handle.net/11449/76881
dc.identifier.wosWOS:000325119600006
dc.language.isoeng
dc.relation.ispartofOrganic and Biomolecular Chemistry
dc.relation.ispartofjcr3.423
dc.relation.ispartofsjr1,281
dc.rights.accessRightsAcesso restrito
dc.sourceScopus
dc.subjectDissociation chemistry
dc.subjectDynamic kinetic resolution
dc.subjectElectrospray ionization mass spectrometry
dc.subjectHydrogen transfer
dc.subjectInnersphere mechanism
dc.subjectMetal coordination
dc.subjectAmines
dc.subjectCatalysts
dc.subjectMass spectrometry
dc.subjectDynamics
dc.titleShvo's catalyst in chemoenzymatic dynamic kinetic resolution of amines-inner or outer sphere mechanism?en
dc.typeArtigo
dcterms.licensehttp://www.rsc.org/AboutUs/Copyright/Authordeposition.asp
unesp.author.lattes1425748916849376[2]
unesp.author.orcid0000-0001-5627-8616[2]
unesp.campusUniversidade Estadual Paulista (Unesp), Instituto de Química, Araraquarapt

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