Hydrothermal synthesis and crystal structure of a copper(ii) coordination polymer with bridging dicarboxylate and diamine ligands

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dc.contributor.authorLegendre, Alexandre de O. [UNESP]
dc.contributor.authorMauro, Antonio Eduardo [UNESP]
dc.contributor.authorNogueira, Vânia Martins [UNESP]
dc.contributor.authorCastellano, Eduardo E.
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniversidade de São Paulo (USP)
dc.date.accessioned2014-05-27T11:23:48Z
dc.date.available2014-05-27T11:23:48Z
dc.date.issued2008-12-01
dc.description.abstractThis work reports on the synthesis of a copper(II) coordination compound with 4,4-oxibis(benzoate) (obb) and trans-1,2- bis(4-pyridyl)ethene (bpe) ligands. The complex was characterized by single-crystal X-ray diffraction, which showed a 3D polymeric structure. Each copper center is surrounded by four oxygen atoms at the basal plane and one nitrogen atom and one copper atom at the axial positions, revealing a distorted octahedral geometry. Four carboxylic groups bridge two copper atoms, forming a cage-like structure, with the distance between the metallic centers being 2.656(1)Å. 2008 © The Japan Society for Analytical Chemistry.en
dc.description.affiliationInstituto de Química de Araraquara São Paulo State University-UNESP, CEP 14800-900, Araraquara, SP
dc.description.affiliationInstituto de Física de São Carlos Universidade de São Paulo-USP, CEP 13560-970, São Carlos, SP
dc.description.affiliationUnespInstituto de Química de Araraquara São Paulo State University-UNESP, CEP 14800-900, Araraquara, SP
dc.identifierhttp://www.jsac.or.jp/cgi-bin/xraystruct/j-abst/24/5/x69/
dc.identifier.citationAnalytical Sciences: X-ray Structure Analysis Online, v. 24, n. 5, 2008.
dc.identifier.issn1348-2238
dc.identifier.lattes3300223970814448
dc.identifier.lattes8980849254118153
dc.identifier.scopus2-s2.0-70450253438
dc.identifier.urihttp://hdl.handle.net/11449/70797
dc.language.isoeng
dc.relation.ispartofAnalytical Sciences: X-ray Structure Analysis Online
dc.rights.accessRightsAcesso restrito
dc.sourceScopus
dc.titleHydrothermal synthesis and crystal structure of a copper(ii) coordination polymer with bridging dicarboxylate and diamine ligandsen
dc.typeNota
unesp.author.lattes3300223970814448[2]
unesp.author.lattes8980849254118153
unesp.author.lattes3123518117881050[1]
unesp.author.orcid0000-0002-2794-5763[1]
unesp.campusUniversidade Estadual Paulista (Unesp), Instituto de Química, Araraquarapt

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