Synthesis and solid-state structural characterization of di-μ-azido-bis[{azido(N, N-diethylethylenediamine)}copper(II)]

Página do item simplificado
dc.contributor.authorCasagrande Jr., Osvaldo L. [UNESP]
dc.contributor.authorKlein, Stanlei Ivair [UNESP]
dc.contributor.authorMauro, Antonio Eduardo [UNESP]
dc.contributor.authorTomita, Koychi [UNESP]
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-27T05:45:59Z
dc.date.available2014-05-27T05:45:59Z
dc.date.issued1989-02-01
dc.description.abstractThe 1:1 mixed-ligand [{Cu(N3)2(diEten)}2] (diEten=N,N-diethylethylenediamine) complex has been synthesized and characterized by i.r. spectroscopy and X-ray diffraction. The compound crystallizes in the triclinic space group P1. Its structure consists of a centrosymmetric Cu2N2 unit whose N atoms belong to end-on azido bridges. Each copper atom is also surrounded by three nitrogen atoms; two from one N, N-diethylethylenediamine, and one from the remaining azide. The five nitrogen atoms altogether occupy the vertices of a slightly distorted trigonal bipyramid, and the azidobridges produced a rather short Cu...Cu distance of 3.37 Å. © 1989 Chapman and Hall Ltd.en
dc.description.affiliationInstituto de Quĩmica de Araraquara UNESP, CxP, 174, Arara quara S. P., 14 800
dc.description.affiliationUnespInstituto de Quĩmica de Araraquara UNESP, CxP, 174, Arara quara S. P., 14 800
dc.format.extent45-47
dc.identifierhttp://dx.doi.org/10.1007/BF01129758
dc.identifier.citationTransition Metal Chemistry, v. 14, n. 1, p. 45-47, 1989.
dc.identifier.doi10.1007/BF01129758
dc.identifier.issn0340-4285
dc.identifier.issn1572-901X
dc.identifier.lattes2545904877423127
dc.identifier.lattes3300223970814448
dc.identifier.scopus2-s2.0-0002095139
dc.identifier.urihttp://hdl.handle.net/11449/63897
dc.language.isoeng
dc.relation.ispartofTransition Metal Chemistry
dc.relation.ispartofjcr1.261
dc.relation.ispartofsjr0,306
dc.rights.accessRightsAcesso restrito
dc.sourceScopus
dc.titleSynthesis and solid-state structural characterization of di-μ-azido-bis[{azido(N, N-diethylethylenediamine)}copper(II)]en
dc.typeArtigo
dcterms.licensehttp://www.springer.com/open+access/authors+rights
unesp.author.lattes2545904877423127
unesp.author.lattes3300223970814448[3]
unesp.campusUniversidade Estadual Paulista (Unesp), Instituto de Química, Araraquarapt

Arquivos

Coleções

Artigos - Química Inorgânica - IQ
Artigos - Físico Química - IQ