Lanthanum cobaltite black pigments with perovskite structure
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In this work La1-xCaxCoO3 (x = 0-0.4) pigments were synthesized by the polymeric precursor method with heat treatments at 700, 800 and 900 C for 4 h. The powders were characterized by colorimetry, UV-vis spectroscopy and powder X-ray diffraction (XRD). The X-ray diffraction patterns showed the presence of a single phase perovskite, changing its structure from rhombohedral to cubic, when calcium was added to the lattice. All of the pigments had a black colour with a strong absorption over the whole of the visible spectrum as a consequence of the different oxidation states of cobalt and the high short-range disorder. The substitution of Ca2+ for La3+ did not influence the pigment colour but decreased its final cost. © 2013 Elsevier Ltd. All rights reserved.
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Black pigment, Cobaltite, Lanthanum, Perovskite, Polymeric precursor method, Solid solution, Lanthanum cobaltite, Perovskite structures, Polymeric precursor methods, Powder X ray diffraction, Strong absorptions, UV-vis spectroscopy, Absorption spectroscopy, Calcium, Cobalt compounds, Color, Lanthanum alloys, Polymers, Solid solutions, Ultraviolet visible spectroscopy, X ray diffraction, X ray powder diffraction
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Inglês
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Dyes and Pigments, v. 98, n. 3, p. 459-463, 2013.
