Kinetic studies on the reactions of Ru(II) tetraammines with CS2N- 3
| dc.contributor.author | Trabuco, Elizeu [UNESP] | |
| dc.contributor.institution | Universidade Estadual Paulista (Unesp) | |
| dc.date.accessioned | 2014-05-27T02:08:08Z | |
| dc.date.available | 2014-05-27T02:08:08Z | |
| dc.date.issued | 1986-12-01 | |
| dc.description.abstract | The kinetics of the reactions of Ru(II) complexes with CS2N- 3 ions were studied spectrophotometrically. The formation rate constants data for trans-[Ru(NH3)4L(CS2N3)] are 2.2 × 102, 1.8 × 10 and 1.3 × 102 M-1 s-1 for L = SO2- 3, HSO- 3 and P(OEt)3), respectively [μ = 1.0 M (NaCF3COO), 25°C]. Under the same experimental conditions, the values of k-1 (specific rate for the aquation reaction) are 1.5 × 10-2, 5.0 × 10-2 and 4.5 × 10 s-1 for L = SO2- 3, HSO- 3 and P(OEt)3, respectively. The free-energy change (ΔG≠) for the systems where L = P(OEt)3 and SO2- 3 are in agreement within the experimental error. It was observed that the affinity of the CS2N- 3 ion decreases with the increasing π-acidity of the auxiliary ligand L. The order of affinity of the CS2N- 3 ion for the Ru(II) center studies is SO2- 3 > HSO- 3 > P(OEt)3 >SO2. © 1986. | en |
| dc.description.affiliation | Instituto de Biociências Letras e Ciências Exatas de São José do Rio Preto UNESP, 15100 Sao Jose do Rio Preto, SP | |
| dc.description.affiliationUnesp | Instituto de Biociências Letras e Ciências Exatas de São José do Rio Preto UNESP, 15100 Sao Jose do Rio Preto, SP | |
| dc.format.extent | 1503-1508 | |
| dc.identifier | http://dx.doi.org/10.1016/S0277-5387(00)84547-7 | |
| dc.identifier.citation | Polyhedron, v. 5, n. 10, p. 1503-1508, 1986. | |
| dc.identifier.doi | 10.1016/S0277-5387(00)84547-7 | |
| dc.identifier.issn | 0277-5387 | |
| dc.identifier.lattes | 6947341745767693 | |
| dc.identifier.scopus | 2-s2.0-46149138803 | |
| dc.identifier.uri | http://hdl.handle.net/11449/63780 | |
| dc.language.iso | eng | |
| dc.relation.ispartof | Polyhedron | |
| dc.relation.ispartofjcr | 2.067 | |
| dc.relation.ispartofsjr | 0,472 | |
| dc.rights.accessRights | Acesso restrito | |
| dc.source | Scopus | |
| dc.title | Kinetic studies on the reactions of Ru(II) tetraammines with CS2N- 3 | en |
| dc.type | Artigo | |
| dcterms.license | http://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy | |
| unesp.author.lattes | 6947341745767693 | |
| unesp.campus | Universidade Estadual Paulista (Unesp), Instituto de Biociências, Letras e Ciências Exatas, São José do Rio Preto | pt |
| unesp.department | Química e Ciências Ambientais - IBILCE | pt |