Chemical and spectroscopic studies of a new palladium(II) complex with N-acetyl-L-cysteine
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2008-01-01
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Taylor & Francis Ltd
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Chemical and spectroscopic studies of a new palladium(II) N-acetyl-L-cysteine complex are described. Elemental analyses for the solid complex are consistent with the formula [Pd(C(5)H(8)NO(3)S)(2)] H(2)O or [Pd(NAC)(2)] H(2)O. Solid-state (13)C nuclear magnetic resonance (NMR), UV-Visible (UV-Vis) and infrared (IR) spectroscopic analyses are consistent with coordination of the ligand to palladium(II) through the nitrogen and sulfur atoms in a square-planar geometry. Thermogravimetric and differential thermal analyses confirmed the composition; final residue was identified as metallic palladium.
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Journal of Coordination Chemistry. Abingdon: Taylor & Francis Ltd, v. 61, n. 22, p. 3666-3673, 2008.